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• W4367601013 endingPage "22444" @default.
• W4367601013 startingPage "22435" @default.
• W4367601013 abstract "In the pursuit of chiral materials with significant chiral recognition effects and stability, various strategies have been explored, among which the integration of metal nanoparticles and chiral metal-organic frameworks (CMOFs) is highly promising. However, metal nanoparticles (MNPs)/CMOFs show high chiral properties but inferior stabilities due to the MNPs being easily detached from the outside layer under certain conditions. Sandwich MOFs@MNPs@CMOF chiral materials can overcome this dilemma because the sandwich structure can maximize the regulation of the chiral interface activity, while the controlled outer layer can stop the MNPs from falling off in the procedure of chiral recognition. Here, a novel sandwich chiral material (d-His-ZIF-8@Au@ZIF-8) was synthesized by a ligand-assisted strategy with a well-defined sandwich morphology and chiral recognition capabilities. The electrochemical chiral recognition showed that d-His-ZIF-8@Au@ZIF-8 was the most efficient for the enantiomer of phenylalanine (Phe). This experiment presents a novel perspective for the fabrication of a chiral electrochemical sensing platform based on a solid sandwich chiral nanocomposite." @default.
• W4367601013 created "2023-05-02" @default.
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• W4367601013 date "2023-05-01" @default.
• W4367601013 modified "2023-10-16" @default.
• W4367601013 title "Design and Electrochemical Chiral Sensing of the Robust Sandwich Chiral Composite <scp>d</scp>-His-ZIF-8@Au@ZIF-8" @default.
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• W4367601013 doi "https://doi.org/10.1021/acsami.3c03947" @default.
• W4367601013 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37126450" @default.
• W4367601013 hasPublicationYear "2023" @default.
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