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- W4367673403 abstract "The reaction of dialane [(dpp-bian)Al–Al(dpp-bian)] (1) (dpp-bian = 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) with N2O results in the formation of oxide [(dpp-bian)Al(μ2-O)2Al(dpp-bian)] (2). The reaction of the thf adduct of 1, [(dpp-bian)(thf)Al–Al(thf)(dpp-bian)] (3), with N2O affords oxo-bridged [(dpp-bian)Al(thf)(μ-O)Al(thf)(dpp-bian)] (4). The addition of carbon dioxide to compound 2 leads to the formation of carbonate [(dpp-bian)Al(μ-O)(μ-CO3)Al(dpp-bian)] (5). Diamagnetic derivatives have been characterized by 1H NMR spectroscopy and paramagnetic compounds by electron paramagnetic resonance spectroscopy; their molecular structures have been established by single-crystal X-ray analysis." @default.
- W4367673403 created "2023-05-03" @default.
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- W4367673403 date "2023-05-02" @default.
- W4367673403 modified "2023-09-29" @default.
- W4367673403 title "Reduction of Nitrous Oxide and Binding of Carbon Dioxide by Acenaphthene-1,2-diimine Aluminum Compounds" @default.
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- W4367673403 doi "https://doi.org/10.1021/acs.organomet.3c00130" @default.
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