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- W4367856356 abstract "Mixed-ligand and anion-templated strategies in constructing metal nanoclusters are intricate and ingenious processes that face challenges to be studied. Herein, we report a cationic [Ag<sub>13</sub>(MoO<sub>4</sub>)<sub>4</sub>(SC<sub>6</sub>H<sub>4</sub><i>i</i>Pr)<sub>2</sub>(dppp)<sub>8</sub>]<sup>3+</sup> (Ag<sub>13</sub>) nanocluster, which is templated using four [MoO<sub>4</sub>]<sup>2−</sup> anions and coprotected by 4-isopropylphenol (<i>i</i>PrC<sub>6</sub>H<sub>4</sub>S<sup>−</sup>) and 1,3-bis (diphenylphosphino) propane (dppp). Two capped (Ag<sub>4</sub>SC<sub>6</sub>H<sub>4</sub><i>i</i>Pr)<sub>2</sub> units connect with the middle Ag@Ag<sub>4</sub> layer via four [MoO<sub>4</sub>]<sup>2−</sup> anion templates to form a three-layer <i>D</i><sub>4<i>h</i></sub>-symmetric structure. An ideal crystallographic fourfold axis passes through the central Ag atom and the S and C atoms of the <i>i</i>PrC<sub>6</sub>H<sub>4</sub>S<sup>−</sup> ligand. The layer stacking generates a nonface-centered cubic (nonFCC) structure. The structure and composition of the Ag<sub>13</sub> nanocluster have been fully characterized. In addition, the solid ultraviolet–visible (UV–vis) spectra show that Ag<sub>13</sub> is a potential narrow-band-gap semiconductor. The photoluminescence (PL) of orange-yellow-light emission is attributed to ligand-to-metal charge transfer. This work has advanced the research on shell engineering of anionic templates and coprotection to assemble high-symmetric Ag nanoclusters." @default.
- W4367856356 created "2023-05-04" @default.
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- W4367856356 date "2023-06-01" @default.
- W4367856356 modified "2023-10-16" @default.
- W4367856356 title "[MoO <sub>4</sub>] <sup>2−</sup>-templated <i>D</i> <sub>4 <i>h</i> </sub>-symmetric sandwich Ag <sub>13</sub> nanocluster coprotected with thiolate and phosphine" @default.
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- W4367856356 doi "https://doi.org/10.26599/pom.2023.9140028" @default.
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