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- W4368371121 abstract "Erbium (Er[Formula: see text] ion exhibits efficient broadband emission at 1.53 [Formula: see text]m (4f optical transition 4I13/2 [Formula: see text] 4I15/2), which is promising to achieve better clarity and deeper penetration depth for biological imaging. However, because of the relatively low luminescent level ( 4 I[Formula: see text], ca. 6500 cm[Formula: see text] and the tendency of being facile to be quenched by high-energy oscillators such as N-H, C-H, or O-H groups, achieving small molecular Er complexes with intense NIR-II luminescence has remained a challenge. In this work, a series of Er[Formula: see text] complexes of porphyrinoids and [Formula: see text]-perhalogenated derivatives caped with auxiliary deuterated Kläui ligands were prepared, namely X-1-Er, X-2-Er and X-cis/trans-3-Er (X = H, F, Cl, Br). Interestingly, most of the [Formula: see text]-perhalogenated Er complexes displayed high overall quantum yields ([Formula: see text] 0.1% in CH 2 Cl 2 and CD 2 Cl 2 ) and long lifetimes ([Formula: see text] 8 [Formula: see text]s in CH 2 Cl 2 and 11 [Formula: see text]s in CD 2 Cl 2 )." @default.
- W4368371121 created "2023-05-05" @default.
- W4368371121 creator A5076944433 @default.
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- W4368371121 date "2023-06-26" @default.
- W4368371121 modified "2023-10-16" @default.
- W4368371121 title "Highly NIR-II luminescent erbium porphyrinoids" @default.
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- W4368371121 doi "https://doi.org/10.1142/s1088424623500943" @default.
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