Matches in SemOpenAlex for { <https://semopenalex.org/work/W4372357882> ?p ?o ?g. }
- W4372357882 endingPage "30731" @default.
- W4372357882 startingPage "30718" @default.
- W4372357882 abstract "Molecular hydrogen (H2) is one of the future energy carriers when replacing fossil sources. Enzymatic systems serve as an inspiration for the design of novel hydrogen evolving catalysts. Though several heterobimetallic Ru systems are known as catalysts for the hydrogen evolution reaction (HER), homogeneous mononuclear Ru systems have not been explored much. Here, a new mononuclear Ru(II) complex [cis-RuCl2(PPh3)2(κ2-TL)] (TL = 2-thiophenyl benzimidazole) possessing distorted octahedral geometry, has been synthesised and characterized as an efficient catalyst for acid-assisted hydrogen evolution by using various spectroscopic techniques as well as quantum chemical calculations. When trifluoroacetic acid is used as the proton source, the complex shows remarkable catalytic activity towards H2 production. Based on the DFT calculations, an EECC mechanism could be proposed for HER, consistent with the assignment of the observed redox transitions." @default.
- W4372357882 created "2023-05-07" @default.
- W4372357882 creator A5017994563 @default.
- W4372357882 creator A5063431038 @default.
- W4372357882 creator A5076936031 @default.
- W4372357882 creator A5083460661 @default.
- W4372357882 date "2023-09-01" @default.
- W4372357882 modified "2023-09-27" @default.
- W4372357882 title "Mono-nuclear ruthenium catalyst for hydrogen evolution" @default.
- W4372357882 cites W1963666284 @default.
- W4372357882 cites W1969243292 @default.
- W4372357882 cites W1971396352 @default.
- W4372357882 cites W1972293646 @default.
- W4372357882 cites W1976804253 @default.
- W4372357882 cites W1980066622 @default.
- W4372357882 cites W1982356449 @default.
- W4372357882 cites W1984392692 @default.
- W4372357882 cites W1987832365 @default.
- W4372357882 cites W1988091937 @default.
- W4372357882 cites W1989205080 @default.
- W4372357882 cites W1991433642 @default.
- W4372357882 cites W1995507794 @default.
- W4372357882 cites W1997770072 @default.
- W4372357882 cites W2000928521 @default.
- W4372357882 cites W2001063720 @default.
- W4372357882 cites W2007258129 @default.
- W4372357882 cites W2019007515 @default.
- W4372357882 cites W2021954807 @default.
- W4372357882 cites W2023271753 @default.
- W4372357882 cites W2023695570 @default.
- W4372357882 cites W2025039040 @default.
- W4372357882 cites W2026815967 @default.
- W4372357882 cites W2030891678 @default.
- W4372357882 cites W2035361999 @default.
- W4372357882 cites W2035643321 @default.
- W4372357882 cites W2036528722 @default.
- W4372357882 cites W2042663882 @default.
- W4372357882 cites W2050662856 @default.
- W4372357882 cites W2055297456 @default.
- W4372357882 cites W2055563809 @default.
- W4372357882 cites W2059494469 @default.
- W4372357882 cites W2060156727 @default.
- W4372357882 cites W2064412542 @default.
- W4372357882 cites W2064871479 @default.
- W4372357882 cites W2065818181 @default.
- W4372357882 cites W2067309983 @default.
- W4372357882 cites W2068453999 @default.
- W4372357882 cites W2072959885 @default.
- W4372357882 cites W2077979133 @default.
- W4372357882 cites W2079436950 @default.
- W4372357882 cites W2079704910 @default.
- W4372357882 cites W2080906302 @default.
- W4372357882 cites W2082037815 @default.
- W4372357882 cites W2084017605 @default.
- W4372357882 cites W2086957099 @default.
- W4372357882 cites W2090135568 @default.
- W4372357882 cites W2092157292 @default.
- W4372357882 cites W2104796556 @default.
- W4372357882 cites W2119533886 @default.
- W4372357882 cites W2125243015 @default.
- W4372357882 cites W2138503485 @default.
- W4372357882 cites W2140138747 @default.
- W4372357882 cites W2151335344 @default.
- W4372357882 cites W2214132227 @default.
- W4372357882 cites W2228940409 @default.
- W4372357882 cites W2326828937 @default.
- W4372357882 cites W2328034507 @default.
- W4372357882 cites W2329763230 @default.
- W4372357882 cites W2342619973 @default.
- W4372357882 cites W2386607147 @default.
- W4372357882 cites W240639126 @default.
- W4372357882 cites W2461067607 @default.
- W4372357882 cites W2468313467 @default.
- W4372357882 cites W2469190439 @default.
- W4372357882 cites W2472879114 @default.
- W4372357882 cites W2473913709 @default.
- W4372357882 cites W2488311164 @default.
- W4372357882 cites W2523466559 @default.
- W4372357882 cites W2534297795 @default.
- W4372357882 cites W2558658892 @default.
- W4372357882 cites W2574987849 @default.
- W4372357882 cites W2582916998 @default.
- W4372357882 cites W2735347617 @default.
- W4372357882 cites W2736581657 @default.
- W4372357882 cites W2757291075 @default.
- W4372357882 cites W2772322343 @default.
- W4372357882 cites W2773653901 @default.
- W4372357882 cites W2785460809 @default.
- W4372357882 cites W2788836959 @default.
- W4372357882 cites W2797404409 @default.
- W4372357882 cites W2805686843 @default.
- W4372357882 cites W2806673097 @default.
- W4372357882 cites W2810131128 @default.
- W4372357882 cites W2891936235 @default.
- W4372357882 cites W2899712481 @default.
- W4372357882 cites W2908015405 @default.
- W4372357882 cites W2913249954 @default.
- W4372357882 cites W2914846970 @default.