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• W4375853504 abstract "An octanuclear vanadium(V) oxide cluster complex, [V8O20(4,4′-tBubpy)4], having a nonionic V8O20 core functionalized with 4,4′-di-tert-butyl-2,2′-bipyridine (4,4′-tBubpy) ligands can be employed for the visible-light photooxidation of alcohols (ROH) by molecular oxygen. In the present reaction, heptanuclear oxido(alkoxido)vanadium(V) complexes, [V7O17(OR)(4,4′-tBubpy)3], generated in situ from [V8O20(4,4′-tBubpy)4] and ROH are proposed to be key catalyst intermediates. An octanuclear vanadium(V) oxide cluster complex, [V8O20(4,4′-tBubpy)4], having a nonionic V8O20 core functionalized with 4,4′-di-tert-butyl-2,2′-bipyridine (4,4′-tBubpy) ligands can be employed for the visible-light photooxidation of alcohols (ROH) by molecular oxygen. In the present reaction, heptanuclear oxido(alkoxido)vanadium(V) complexes, [V7O17(OR)(4,4′-tBubpy)3], generated in situ from [V8O20(4,4′-tBubpy)4] and ROH are proposed to be key catalyst intermediates." @default.
• W4375853504 created "2023-05-10" @default.
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• W4375853504 date "2023-06-05" @default.
• W4375853504 modified "2023-09-29" @default.
• W4375853504 title "A Nonionic Octanuclear Vanadium(V) Oxide Cluster Complex as a Precatalyst for Visible-light Photooxidation of Alcohols under O₂ Atmosphere" @default.
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• W4375853504 doi "https://doi.org/10.1246/cl.230144" @default.
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