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- W4375905912 abstract "A series of novel bis(imino)pyridine nickel(II) dichloride complexes, with the bis(imino)pyridine ligands containing electron-withdrawing groups (F, Cl, Br, CF3), have been prepared and characterized by elemental analysis and NMR spectroscopy. All complexes exhibit paramagnetically shifted 1H NMR spectra, indicative of the high-spin (S = 1) state of the d8 nickel(II) central atom. These complexes have been found to be highly active catalysts of vinyl-type norbornene polymerization upon activation with MAO, displaying activities up to 1.16 × 107 g of PNB (mol of cat.)−1 h–1 (the highest ever reported for norbornene polymerizations on bis(imino)pyridine nickel complexes) and yielding high-molecular-weight polynorbornene (Mw up to 4.5 × 106). X-ray structures for some of the nickel complexes are reported." @default.
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- W4375905912 date "2012-01-23" @default.
- W4375905912 modified "2023-10-16" @default.
- W4375905912 title "Vinyl Polymerization of Norbornene on Nickel Complexes with Bis(imino)pyridine Ligands Containing Electron-Withdrawing Groups" @default.
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- W4375905912 doi "https://doi.org/10.1021/om201213v" @default.
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