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W4375931867 abstract "Nichtaktivierte CH3-Gruppen in 2-Oxazolinen werden durch kostengünstige Oxidationsmittel wie tert-Butylperoxyacetat und Lauroylperoxid in Gegenwart katalytischer Mengen Pd(OAc)2 oxidiert. Carboxyanhydride sind für die Oxidation der Pd-C-Bindungen und die Regenerierung von Pd(OAc)2 unentbehrlich. Durch Verwendung von [D6]Ac2O als Solvens lässt sich zeigen, dass die in das Produkt eingebaute Acetylgruppe von Acetanhydrid stammt." @default.
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W4375931867 date "2005-11-16" @default.
W4375931867 modified "2023-10-11" @default.
W4375931867 title "Pd-Catalyzed Stereoselective Oxidation of Methyl Groups by Inexpensive Oxidants under Mild Conditions: A Dual Role for Carboxylic Anhydrides in Catalytic CH Bond Oxidation" @default.
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W4375931867 doi "https://doi.org/10.1002/ange.200502767" @default.
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