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- W4375954705 abstract "Fluorination of oximes with the relatively mild diethylaminosulfur trifluoride/tetrahydrofuran (DAST–THF) system affords imidoyl fluorides. These compounds were isolated, and their structures were confirmed by X-ray single-crystal structure analysis. Reaction of imidoyl fluorides with various nucleophiles efficiently afforded amides, amidines, thioamides, and amine derivatives in high yields. Furthermore, one-pot reaction of in situ generated imidoyl fluorides from oximes was also applicable to efficient synthesis of these products. The oxime stereochemistry and acid-labile protecting group remained intact in this system." @default.
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- W4375954705 date "2023-05-09" @default.
- W4375954705 modified "2023-10-02" @default.
- W4375954705 title "Isolation and Reactions of Imidoyl Fluorides Generated from Oxime Using the Diethylaminosulfur Trifluoride/Tetrahydrofuran (DAST–THF) System" @default.
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- W4375954705 doi "https://doi.org/10.1021/acs.orglett.3c01063" @default.
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