Matches in SemOpenAlex for { <https://semopenalex.org/work/W4375954803> ?p ?o ?g. }
- W4375954803 endingPage "6961" @default.
- W4375954803 startingPage "6955" @default.
- W4375954803 abstract "Chiral sulfoxides are valuable in the fields of medicinal chemistry and organic synthesis. A recycle photoreactor utilizing the concept of deracemization, where a racemate is converted into a pure enantiomer, is developed and successfully applied in the syntheses of chiral alkyl aryl sulfoxides. The recycling system consists of rapid photoracemization using an immobilized photosensitizer and separation of the enantiomers via chiral high-performance liquid chromatography, and the desired pure chiral sulfoxides are obtained after 4-6 cycles. The key to the success of the system is the photoreactor site, wherein the photosensitizer 2,4,6-triphenylpyrylium is immobilized on the resin and irradiated (405 nm) to enable the rapid photoracemizations of the sulfoxides. As the green recycle photoreactor requires no chiral components, it should be a useful alternative system for application in producing chiral compounds." @default.
- W4375954803 created "2023-05-10" @default.
- W4375954803 creator A5005565965 @default.
- W4375954803 creator A5013189215 @default.
- W4375954803 creator A5043142016 @default.
- W4375954803 creator A5048807497 @default.
- W4375954803 creator A5052485344 @default.
- W4375954803 creator A5057380612 @default.
- W4375954803 creator A5069583730 @default.
- W4375954803 creator A5077482052 @default.
- W4375954803 creator A5080704857 @default.
- W4375954803 creator A5082194179 @default.
- W4375954803 creator A5085106104 @default.
- W4375954803 creator A5092344828 @default.
- W4375954803 date "2023-05-08" @default.
- W4375954803 modified "2023-09-30" @default.
- W4375954803 title "Conversion of Racemic Alkyl Aryl Sulfoxides into Pure Enantiomers Using a Recycle Photoreactor: Tandem Use of Chromatography on Chiral Support and Photoracemization on Solid Support" @default.
- W4375954803 cites W1975230391 @default.
- W4375954803 cites W1976451123 @default.
- W4375954803 cites W1984958754 @default.
- W4375954803 cites W1996941025 @default.
- W4375954803 cites W1998045381 @default.
- W4375954803 cites W2006603931 @default.
- W4375954803 cites W2021245275 @default.
- W4375954803 cites W2021835088 @default.
- W4375954803 cites W2022776040 @default.
- W4375954803 cites W2024708363 @default.
- W4375954803 cites W2043651271 @default.
- W4375954803 cites W2049530936 @default.
- W4375954803 cites W2058984762 @default.
- W4375954803 cites W2061833734 @default.
- W4375954803 cites W2072633183 @default.
- W4375954803 cites W2073802295 @default.
- W4375954803 cites W2091911175 @default.
- W4375954803 cites W2095287593 @default.
- W4375954803 cites W2101685546 @default.
- W4375954803 cites W2117418354 @default.
- W4375954803 cites W2119007778 @default.
- W4375954803 cites W2124270918 @default.
- W4375954803 cites W2167426231 @default.
- W4375954803 cites W2315631672 @default.
- W4375954803 cites W2320331450 @default.
- W4375954803 cites W2322086065 @default.
- W4375954803 cites W2325929319 @default.
- W4375954803 cites W2333612799 @default.
- W4375954803 cites W2469460246 @default.
- W4375954803 cites W2548041712 @default.
- W4375954803 cites W2739688203 @default.
- W4375954803 cites W2808643232 @default.
- W4375954803 cites W2950283532 @default.
- W4375954803 cites W2951196674 @default.
- W4375954803 cites W2951718913 @default.
- W4375954803 cites W2952850914 @default.
- W4375954803 cites W2953208322 @default.
- W4375954803 cites W2982846010 @default.
- W4375954803 cites W3000352472 @default.
- W4375954803 cites W3004720557 @default.
- W4375954803 cites W3022977533 @default.
- W4375954803 cites W3085975422 @default.
- W4375954803 cites W3194880615 @default.
- W4375954803 cites W3216100569 @default.
- W4375954803 cites W4200056047 @default.
- W4375954803 cites W4220702651 @default.
- W4375954803 cites W4224138019 @default.
- W4375954803 cites W4230603398 @default.
- W4375954803 cites W4244460765 @default.
- W4375954803 cites W4281718622 @default.
- W4375954803 cites W4283321902 @default.
- W4375954803 cites W89453885 @default.
- W4375954803 cites W1977998430 @default.
- W4375954803 doi "https://doi.org/10.1021/acs.joc.3c00265" @default.
- W4375954803 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37155937" @default.
- W4375954803 hasPublicationYear "2023" @default.
- W4375954803 type Work @default.
- W4375954803 citedByCount "0" @default.
- W4375954803 crossrefType "journal-article" @default.
- W4375954803 hasAuthorship W4375954803A5005565965 @default.
- W4375954803 hasAuthorship W4375954803A5013189215 @default.
- W4375954803 hasAuthorship W4375954803A5043142016 @default.
- W4375954803 hasAuthorship W4375954803A5048807497 @default.
- W4375954803 hasAuthorship W4375954803A5052485344 @default.
- W4375954803 hasAuthorship W4375954803A5057380612 @default.
- W4375954803 hasAuthorship W4375954803A5069583730 @default.
- W4375954803 hasAuthorship W4375954803A5077482052 @default.
- W4375954803 hasAuthorship W4375954803A5080704857 @default.
- W4375954803 hasAuthorship W4375954803A5082194179 @default.
- W4375954803 hasAuthorship W4375954803A5085106104 @default.
- W4375954803 hasAuthorship W4375954803A5092344828 @default.
- W4375954803 hasBestOaLocation W43759548031 @default.
- W4375954803 hasConcept C146686406 @default.
- W4375954803 hasConcept C159985019 @default.
- W4375954803 hasConcept C161790260 @default.
- W4375954803 hasConcept C178790620 @default.
- W4375954803 hasConcept C185592680 @default.
- W4375954803 hasConcept C192562407 @default.
- W4375954803 hasConcept C21951064 @default.
- W4375954803 hasConcept C2777814067 @default.
- W4375954803 hasConcept C2780263894 @default.