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• W4375955088 abstract "Nonexponential relaxations are universal characteristics for glassy materials. There is a well-known hypothesis that nonexponential relaxation peaks are composed of a series of exponential events, which have not been verified. In this Letter, we discover the exponential relaxation events during the recovery process using a high-precision nanocalorimetry, which are universal for metallic glasses and organic glasses. The relaxation peaks can be well fitted by the exponential Debye function with a single activation energy. The activation energy covers a broad range from α relaxation to β relaxation and even the fast γ/β' relaxation. We obtain the complete spectrum of the exponential relaxation peaks over a wide temperature range from 0.63Tg to 1.03Tg, which provides solid evidence that nonexponential relaxation peaks can be decomposed into exponential relaxation units. Furthermore, the contribution of different relaxation modes in the nonequilibrium enthalpy space is measured. These results open a door for developing the thermodynamics of nonequilibrium physics and for precisely modulating the properties of glasses by controlling the relaxation modes." @default.
• W4375955088 created "2023-05-10" @default.
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• W4375955088 date "2023-05-08" @default.
• W4375955088 modified "2023-10-13" @default.
• W4375955088 title "Detecting the exponential relaxation spectrum in glasses by high-precision nanocalorimetry" @default.
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• W4375955088 doi "https://doi.org/10.1073/pnas.2302776120" @default.
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• W4375955088 hasPublicationYear "2023" @default.
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