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- W4376133006 abstract "Cumulenes have attracted considerable attention due to their unique structural and electronic properties. Despite their high potential for constructing condensed π-conjugated molecules, the synthetic utility of longer cumulenes remains to be established owing to their inherently high reactivity. Conjugated bisbutatrienes having two cumulene moieties linked by a spacer as a mimic of a longer cumulene were evaluated. Here, the synthesis and characterization of hexafluorocyclopentane-bridged bisbutatrienes are described. These bisbutatrienes underwent various cyclizations, to construct the unique π-extended frameworks inaccessible by other methodologies. The bisbutatrienes were converted into fulvenes, pentalene, germacycle, and benzocyclobutene under various conditions. Furthermore, a cyclooctatetraene derivative was synthesized by a one-step dimerization of the bisbutatriene." @default.
- W4376133006 created "2023-05-12" @default.
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- W4376133006 date "2023-06-02" @default.
- W4376133006 modified "2023-10-15" @default.
- W4376133006 title "Synthesis and Characterization of Hexafluorocyclopentane‐Bridged Bisbutatrienes as Models for Longer Cumulenes: Various Transformations for the Construction of π‐Conjugated Frameworks" @default.
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- W4376133006 doi "https://doi.org/10.1002/chem.202301255" @default.
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