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- W4376134714 abstract "Lubricant oils can autoxidize due to contact with air and can be accelerated by heat and catalyzed with metal ion impurities. Therefore, new antioxidant additives are needed. Carbon nanomaterials exhibit excellent thermal oxidation resistance and can act as additives for lubricant oils to extend their operational lifetime. In this work, we studied the autoxidation behavior of a mixture of C60/C70 clusters in mineral oil (MO) containing different amounts of toluene during mixing. The addition of toluene during mixing increased the ratio of C60/C70 and the cluster size. The oil-fullerene mixtures (MO/C60/70) were heated at 150 °C for 48 h under magnetic stirring. FTIR analysis and TGA showed that the initial oxidation rate and high thermal oxidation (ca. 375 °C) decreased with the addition of fullerenes. Ball on disk friction tests showed that fullerenes effectively reduced the friction coefficient, favored by smaller C60/70 clusters. The obtained results demonstrate that small fullerene clusters with high C70 content can be achieved without the addition of toluene in mineral oil and exhibit higher antioxidation, and lower friction coefficient. Thus, fullerenes could be of high interest as an additive for lubricant oils." @default.
- W4376134714 created "2023-05-12" @default.
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- W4376134714 date "2023-05-11" @default.
- W4376134714 modified "2023-10-18" @default.
- W4376134714 title "Tuning Autoxidation and Friction of Mineral Oil by Fullerene Cluster Properties" @default.
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- W4376134714 doi "https://doi.org/10.1021/acs.iecr.3c00358" @default.
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