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- W4376272287 abstract "The slag composition corresponding to different coals varies significantly, which directly affects the operation of industrial entrained flow gasifiers and the service life of refractory bricks. In this study, the corrosion resistance of several typical coal slags for gasification on high chromia refractory bricks was comparatively investigated by static laboratory crucible tests and thermodynamic simulations. The results demonstrated that the corrosion degree of high chromia refractory by different coal slags was high-Ca/Na slag > high-Fe slag > high-Si/Al slag. The surface structure of the refractory was relatively flat after corrosion by high-Si/Al slag, and the primary corrosion reaction was the partial dissolution of the matrix by the slag. High-Fe slag was prone to the precipitation of iron phases as well as the formation of (Mg, Fe) (Al, Cr)2O4 composite spinel layer at the slag/refractory interface. The high-Ca/Na slag was susceptible to react with the refractory to yield a low melting point phase, which led to the destruction of the matrix structure of the refractory and an isolated distribution of particles. In addition, the reaction of monoclinic ZrO2 in the refractory with CaO in the slag to form calcium zirconate, which loosens its phase toughening effect, was the primary factor that aggravated the refractory corrosion. © 2023 The Chemical Industry and Engineering Society of China, and Chemical Industry Press Co., Ltd.. All rights reserved." @default.
- W4376272287 created "2023-05-13" @default.
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- W4376272287 date "2023-05-01" @default.
- W4376272287 modified "2023-10-16" @default.
- W4376272287 title "Effect of slag composition on corrosion resistance of high chromia refractory bricks for industrial entrained-flow gasifier" @default.
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- W4376272287 doi "https://doi.org/10.1016/j.cjche.2023.03.026" @default.
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