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- W4376274845 abstract "Sclareolide was developed as an efficient C-nucleophilic reagent for an asymmetric Mannich addition reaction with a series of N-tert-butylsulfinyl aldimines. The Mannich reaction was carried out under mild conditions, affording the corresponding aminoalkyl sclareolide derivatives with up to 98% yield and 98:2:0:0 diastereoselectivity. Furthermore, the reaction could be performed on a gram scale without any reduction in yield and diastereoselectivity. Additionally, deprotection of the obtained Mannich addition products to give the target sclareolide derivatives bearing a free N-H group was demonstrated. In addition, target compounds 4-6 were subjected to an antifungal assay in vitro, which showed considerable antifungal activity against forest pathogenic fungi." @default.
- W4376274845 created "2023-05-13" @default.
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- W4376274845 date "2023-05-12" @default.
- W4376274845 modified "2023-10-01" @default.
- W4376274845 title "Synthesis of Aminoalkyl Sclareolide Derivatives and Antifungal Activity Studies" @default.
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- W4376274845 doi "https://doi.org/10.3390/molecules28104067" @default.
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