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- W4376278082 abstract "Direct C−H bond arylation is a highly effective method for synthesizing arylated heteroaromatics. This method reduces synthetic steps and minimizes the formation of impurities. We report an air and moisture-stable iminopyridine-based α-diimine nickel (II) complex for direct C5-H bond arylation of thiazole derivatives. Under low catalyst loading and performing the reactions at lower temperatures (80 °C) under aerobic conditions, we produced mono- and diarylated thiazole units. Competition experiments and density functional theory calculations (DFT) revealed that the mechanism of C−H activation in 4-methylthiazole involves electrophilic aromatic substitution." @default.
- W4376278082 created "2023-05-13" @default.
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- W4376278082 date "2023-05-12" @default.
- W4376278082 modified "2023-10-16" @default.
- W4376278082 title "Regioselective Direct C−H Bond (Hetero)arylation of Thiazoles Enabled by a Novel Iminopyridine-Based α‐Diimine Nickel(II) Complex Evaluated by DFT Studies." @default.
- W4376278082 doi "https://doi.org/10.26434/chemrxiv-2023-tn92w" @default.
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