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- W4376278843 abstract "Designing permanent microporosity in a glassy state of coordination polymer (CP) and metal–organic framework (MOF) has been challenging due to densification of the structures upon vitrification. Here, we propose a new approach to create porosity in CP/MOF glasses derived from nonporous 1D crystal structures. Glassy states of two dense 1D crystal structures [Ag2(cis-dbe) (CF3SO3)2] and [Ag2(cis-dbe) (CF3CO2)2], where cis-dbe = cis-1,2-dicyano-1,2-bis(2,4,5-trimethyl-3-thienyl)ethene, were prepared by ball milling. Glass structures and dynamics were characterized by synchrotron X-ray, solid-state NMR, and thermal analyses. Loosened assembly of 1D chains through glass formation enabled representation of permanent microporosity and resulted in selective gas sorption behaviors of acetylene over CO2. It elucidated that the property of gas uptake is affected by the glass dynamics and interaction with anions. Reversible photochromism of cis-dbe is preserved in the glasses, leading to multi-functional glass materials." @default.
- W4376278843 created "2023-05-13" @default.
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- W4376278843 date "2023-05-12" @default.
- W4376278843 modified "2023-10-15" @default.
- W4376278843 title "Formation of Porosity toward Acetylene upon Vitrification of Non-porous Photochromic Coordination Polymer Crystals" @default.
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- W4376278843 doi "https://doi.org/10.1021/acs.chemmater.2c03510" @default.
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