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- W4376453148 endingPage "8117" @default.
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- W4376453148 abstract "Caught in the act: N-Heterocyclic carbene copper(I) complexes (1; IPr=1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) serve as an excellent catalyst for the carboxylation of alkylboranes (2; R=alkyl) with CO2 to afford a variety of functionalized carboxylic acids (3) in high yields. A novel copper methoxide/alkylborane adduct (A) and its subsequent CO2 insertion product (B) have been isolated and shown to be true active catalyst species." @default.
- W4376453148 created "2023-05-14" @default.
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- W4376453148 date "2011-07-07" @default.
- W4376453148 modified "2023-10-17" @default.
- W4376453148 title "Carboxylation of Alkylboranes by N-Heterocyclic Carbene Copper Catalysts: Synthesis of Carboxylic Acids from Terminal Alkenes and Carbon Dioxide" @default.
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- W4376453148 doi "https://doi.org/10.1002/anie.201101769" @default.
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