FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4376505385> ?p ?o ?g. }

• W4376505385 abstract "Metal-organic frameworks (MOFs) as a promising platform for electrocatalytic CO2 conversion are still restricted by the low efficiency or unsatisfied selectivity for desired products. Herein, zirconium-based porphyrinic MOF hollow nanotubes with Cd sites (Cd-PCN-222HTs) are reported for electrocatalytic CO2 -to-CO conversion. The dispersed Cd species are anchored in PCN-222HTs and coordinated by N atoms of porphyrin structures. It is discovered that Cd-PCN-222HTs have glorious electrocatalytic activity for selective CO production in ionic liquid-water (H2 O)-acetonitrile (MeCN) electrolyte. The CO Faradaic efficiency (FECO ) of >80% could be maintained in a wide potential range from -2.0 to -2.4 V versus Ag/Ag+ , and the maximum current density could reach 68.0 mA cm-2 at -2.4 V versus Ag/Ag+ with a satisfied turnover frequency of 26 220 h-1 . The enhanced efficiency of electrocatalytic CO2 conversion of Cd-PCN-222HTs is closely related to its hollow structure, anchored Cd species, and good synergistic effect with electrolyte. The density functional theory calculations indicate that the dispersed Cd sites anchored in PCN-222HTs not only favor the formation of *COOH intermediate but also hinder the hydrogen evolution reaction, resulting in high activity of electrocatalytic CO2 -to-CO conversion." @default.
• W4376505385 created "2023-05-15" @default.
• W4376505385 creator A5000696036 @default.
• W4376505385 creator A5043126719 @default.
• W4376505385 creator A5055563788 @default.
• W4376505385 creator A5060162962 @default.
• W4376505385 creator A5070474364 @default.
• W4376505385 creator A5076156463 @default.
• W4376505385 creator A5085836074 @default.
• W4376505385 creator A5087742625 @default.
• W4376505385 creator A5088438669 @default.
• W4376505385 date "2023-05-13" @default.
• W4376505385 modified "2023-10-14" @default.
• W4376505385 title "Enhanced the Efficiency of Electrocatalytic CO₂‐to‐CO Conversion by Cd Species Anchored into Metal‐Organic Framework" @default.
• W4376505385 cites W1971670691 @default.
• W4376505385 cites W1994204840 @default.
• W4376505385 cites W2011564123 @default.
• W4376505385 cites W2014464559 @default.
• W4376505385 cites W2125453535 @default.
• W4376505385 cites W2137818170 @default.
• W4376505385 cites W2155579681 @default.
• W4376505385 cites W2340814919 @default.
• W4376505385 cites W2427325384 @default.
• W4376505385 cites W2731595636 @default.
• W4376505385 cites W2761553887 @default.
• W4376505385 cites W2765658313 @default.
• W4376505385 cites W2791036277 @default.
• W4376505385 cites W2791476032 @default.
• W4376505385 cites W2794717324 @default.
• W4376505385 cites W2799653601 @default.
• W4376505385 cites W2799765175 @default.
• W4376505385 cites W2802238712 @default.
• W4376505385 cites W2804235153 @default.
• W4376505385 cites W2888443677 @default.
• W4376505385 cites W2895819610 @default.
• W4376505385 cites W2897574808 @default.
• W4376505385 cites W2913130213 @default.
• W4376505385 cites W2922247811 @default.
• W4376505385 cites W2942998504 @default.
• W4376505385 cites W2954103758 @default.
• W4376505385 cites W2954959763 @default.
• W4376505385 cites W2970262065 @default.
• W4376505385 cites W2998402750 @default.
• W4376505385 cites W3044594215 @default.
• W4376505385 cites W3046651813 @default.
• W4376505385 cites W3082702904 @default.
• W4376505385 cites W3091976992 @default.
• W4376505385 cites W3097335124 @default.
• W4376505385 cites W3099844170 @default.
• W4376505385 cites W3113233278 @default.
• W4376505385 cites W3128327115 @default.
• W4376505385 cites W3129214233 @default.
• W4376505385 cites W3136829626 @default.
• W4376505385 cites W3155571755 @default.
• W4376505385 cites W3158022389 @default.
• W4376505385 cites W3182938533 @default.
• W4376505385 cites W3185167134 @default.
• W4376505385 cites W3193396115 @default.
• W4376505385 cites W3195795879 @default.
• W4376505385 cites W3212035902 @default.
• W4376505385 cites W4200080230 @default.
• W4376505385 cites W4206918869 @default.
• W4376505385 cites W4210407212 @default.
• W4376505385 cites W4210850812 @default.
• W4376505385 cites W4220882057 @default.
• W4376505385 cites W4282963322 @default.
• W4376505385 cites W4310022646 @default.
• W4376505385 cites W4313340037 @default.
• W4376505385 doi "https://doi.org/10.1002/smll.202301319" @default.
• W4376505385 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37178410" @default.
• W4376505385 hasPublicationYear "2023" @default.
• W4376505385 type Work @default.
• W4376505385 citedByCount "0" @default.
• W4376505385 crossrefType "journal-article" @default.
• W4376505385 hasAuthorship W4376505385A5000696036 @default.
• W4376505385 hasAuthorship W4376505385A5043126719 @default.
• W4376505385 hasAuthorship W4376505385A5055563788 @default.
• W4376505385 hasAuthorship W4376505385A5060162962 @default.
• W4376505385 hasAuthorship W4376505385A5070474364 @default.
• W4376505385 hasAuthorship W4376505385A5076156463 @default.
• W4376505385 hasAuthorship W4376505385A5085836074 @default.
• W4376505385 hasAuthorship W4376505385A5087742625 @default.
• W4376505385 hasAuthorship W4376505385A5088438669 @default.
• W4376505385 hasConcept C118792377 @default.
• W4376505385 hasConcept C123480859 @default.
• W4376505385 hasConcept C130349721 @default.
• W4376505385 hasConcept C147789679 @default.
• W4376505385 hasConcept C150394285 @default.
• W4376505385 hasConcept C154881586 @default.
• W4376505385 hasConcept C161790260 @default.
• W4376505385 hasConcept C17525397 @default.
• W4376505385 hasConcept C178790620 @default.
• W4376505385 hasConcept C179104552 @default.
• W4376505385 hasConcept C179366358 @default.
• W4376505385 hasConcept C185592680 @default.
• W4376505385 hasConcept C191897082 @default.
• W4376505385 hasConcept C192562407 @default.
• W4376505385 hasConcept C2777463227 @default.
• W4376505385 hasConcept C2779480358 @default.
• W4376505385 hasConcept C33989665 @default.

• next