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- W4376587921 abstract "C7-Arylated pyrazolo[1,5-a]azines are important structural motifs with profound applications in drug and material research. Here, we report a general and straighforward synthesis of these bi(hetero)aryls via palladium-catalyzed direct C−H arylation, employing low-cost and abundant (hetero)aryl chlorides as the aryl source. The catalytic system is robust and covers a wide substrate scope regarding heteroarenes as well as (hetero)aryl chlorides, with possible extension to the C−H arylation of [1,2,4]triazolo[1,5-a]pyrimidines. This study also presents a rare example of using (hetero)aryl chlorides for the direct C−H arylation of six-membered heteroarenes." @default.
- W4376587921 created "2023-05-17" @default.
- W4376587921 creator A5045455627 @default.
- W4376587921 date "2023-07-07" @default.
- W4376587921 modified "2023-09-24" @default.
- W4376587921 title "Direct C7‐H Arylation of Pyrazolo[1,5‐<i>a</i>]azines with Aryl Chlorides" @default.
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- W4376587921 doi "https://doi.org/10.1002/chem.202301485" @default.
- W4376587921 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37183726" @default.
- W4376587921 hasPublicationYear "2023" @default.
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