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- W4376604448 abstract "The LiCl–KCl–CsCl eutectic salt is expected to be used as a melt medium for the pyrochemical process of spent fuels because of its low melting point properties that reduce the temperature resistance requirements of the equipment. In this work, the electrochemical behaviors of La(III), Ce(III), and Nd(III) ions in the LiCl–KCl–CsCl eutectic salt in the range of 563–683 K were investigated, and it was found that the difficulty of cathodic passivation was in the order of La(III) < Ce(III) < Nd(III). Cyclic voltammetry (CV) and chronopotentiometry (CP) methods were conducted to determine the diffusion coefficients of La(III), Ce(III), and Nd(III). The corresponding diffusion activation energies were also calculated. It was also found that the passivation phenomenon does not affect the equilibrium potentials of La(III), Ce(III), and Nd(III), so we determined the apparent electrode potentials of La(III) and Ce (III) in the range of 563–683 K and Nd(III) in the range of 623–683 K by the galvanostatic voltammetry (GV) method. Finally, Ce and Nd metals were successfully extracted by potentiostatic electrolysis at 563 K for 4 h." @default.
- W4376604448 created "2023-05-17" @default.
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- W4376604448 date "2023-05-15" @default.
- W4376604448 modified "2023-10-16" @default.
- W4376604448 title "Electrochemical Behaviors and Extraction of Ln(III) (Ln = La, Ce, Nd) Ions in LiCl–KCl–CsCl Eutectic Salts at Low Temperatures" @default.
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- W4376604448 doi "https://doi.org/10.1021/acssuschemeng.3c01474" @default.
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