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- W4376605612 endingPage "11414" @default.
- W4376605612 startingPage "11402" @default.
- W4376605612 abstract "Sensitized triplet–triplet annihilation upconversion is a promising strategy to use visible light for chemical reactions requiring the energy input of UV photons. This strategy avoids unsafe ultraviolet light sources and can mitigate photo-damage and provide access to reactions, for which filter effects hamper direct UV excitation. Here, we report a new approach to make blue-to-UV upconversion more amenable to photochemical applications. The tethering of a naphthalene unit to a cyclometalated iridium(III) complex yields a bichromophore with a high triplet energy (2.68 eV) and a naphthalene-based triplet reservoir featuring a lifetime of 72.1 μs, roughly a factor of 20 longer than the photoactive excited state of the parent iridium(III) complex. In combination with three different annihilators, consistently lower thresholds for the blue-to-UV upconversion to crossover from a quadratic into a linear excitation power dependence regime were observed with the bichromophore compared to the parent iridium(III) complex. The upconversion system composed of the bichromophore and the 2,5-diphenyloxazole annihilator is sufficiently robust under long-term blue irradiation to continuously provide a high-energy singlet-excited state that can drive chemical reactions normally requiring UV light. Both photoredox and energy transfer catalyses were feasible using this concept, including the reductive N–O bond cleavage of Weinreb amides, a C–C coupling reaction based on reductive aryl debromination, and two Paternò–Büchi [2 + 2] cycloaddition reactions. Our work seems relevant in the context of developing new strategies for driving energetically demanding photochemistry with low-energy input light." @default.
- W4376605612 created "2023-05-17" @default.
- W4376605612 creator A5000683714 @default.
- W4376605612 creator A5006064125 @default.
- W4376605612 creator A5019575526 @default.
- W4376605612 creator A5042264834 @default.
- W4376605612 creator A5056803015 @default.
- W4376605612 date "2023-05-15" @default.
- W4376605612 modified "2023-10-14" @default.
- W4376605612 title "Metal–Organic Bichromophore Lowers the Upconversion Excitation Power Threshold and Promotes UV Photoreactions" @default.
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