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• W4376608764 abstract "Diamond single crystals showing Infra-red features of pressurized CO2-I phase were studied using Transmission Electron Microscopy (TEM) and tomography. Numerous O-containing precipitates with sizes up to 45 nm are observed. The absolute majority of these precipitates decorate dislocation loops or are located inside them; individual scattered precipitates are also present. Morphology of the precipitates varies from quasi-isometric octahedra to highly flattened elongated ones. Close association of the precipitates with the dislocation loops implies their formation by exsolution of oxygen impurity from diamond lattice; the size distribution of the precipitates suggests that the equilibrium state is not yet reached. Presumably, the morphology and precise chemical composition depend on P-T-t evolution of the diamond crystal and corresponding changes in oxygen supersaturation in the lattice. The CO2-containing diamonds often contain micron-sized hexagonal lamellar inclusions. TEM investigation of a lamellae reveals that it consists of high quality graphite showing partial epitaxial relation with comprising diamond. The gap between the graphite and diamond may be enriched with oxygen impurity." @default.
• W4376608764 created "2023-05-17" @default.
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• W4376608764 date "2023-06-01" @default.
• W4376608764 modified "2023-09-27" @default.
• W4376608764 title "Exsolution of oxygen impurity from diamond lattice and formation of pressurized CO2-I precipitates" @default.
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• W4376608764 doi "https://doi.org/10.1016/j.cartre.2023.100270" @default.
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