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- W4376616900 abstract "An efficient protocol for the asymmetric synthesis of unnatural amino acids is realized through photoredox-mediated C–O bond activation of oxalate esters derived from aliphatic alcohols as the radical precursors. The developed system uses chiral glyoxylate-derived N-sulfinyl imine as the radical acceptor and allows quick access to a range of functionalized unnatural amino acids through an atom-economical redox-neutral process with CO2 as the only stoichiometric by-product." @default.
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- W4376616900 date "2023-05-15" @default.
- W4376616900 modified "2023-09-30" @default.
- W4376616900 title "Asymmetric Synthesis of Unnatural α-Amino Acids through Photoredox-Mediated C–O Bond Activation of Aliphatic Alcohols" @default.
- W4376616900 doi "https://doi.org/10.26434/chemrxiv-2023-dnbpx" @default.
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