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- W4376871103 abstract "A methodology for the construction of sterically congested quaternary centers via the trapping of vinyl carbocations with silyl ketene acetals is disclosed. This main group-catalyzed α-vinylation reaction is advantageous as methods to access these congested motifs are limited. Moreover, β,γ-unsaturated carbonyl moieties and tetrasubstituted alkenes are present in various bioactive natural products and pharmaceuticals, and this catalytic platform offers a means of accessing them using simple and inexpensive materials." @default.
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- W4376871103 date "2023-05-16" @default.
- W4376871103 modified "2023-09-27" @default.
- W4376871103 title "α-Vinylation of Ester Equivalents via Main Group Catalysis for the Construction of Quaternary Centers" @default.
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- W4376871103 doi "https://doi.org/10.1021/acs.orglett.3c00535" @default.
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