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- W4376872155 abstract "The Truce-Smiles rearrangement is an intramolecular SN Ar reaction, enabling the formation of a new arene carbon-carbon bond with sufficiently strong carbon-centered nucleophile. Reported here are ortho-tosylmethylene functionalized diaryliodonium salts, which can undergo an unprecedented Truce-Smiles rearrangement in ionic liquids, resulting in sulfonyl-substituted ortho-iodo diarylmethanes as a powerful class of building blocks in chemical synthesis. The protocol features aryliodo moiety as a hyper nucleofuge, facilitating the formation of Meisenheimer complex within the migratory system." @default.
- W4376872155 created "2023-05-18" @default.
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- W4376872155 date "2023-06-06" @default.
- W4376872155 modified "2023-10-17" @default.
- W4376872155 title "Truce‐Smiles Rearrangement of Diaryliodonium Salts in Ionic Liquids" @default.
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- W4376872155 doi "https://doi.org/10.1002/anie.202304897" @default.
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