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- W4376872279 abstract "The eco-corona on microplastics refers to the initial layer of biomolecular compounds adsorbed onto the surface after environmental exposure. The formation and composition of the eco-corona in soils have attracted relatively little attention; however, the eco-corona has important implications for the fate and impacts of microplastics and co-occurring chemical contaminants. Here, it was demonstrated that the formation of the eco-corona on polyethylene microplastics exposed to water-extractable soil metabolites (WESMs) occurs quite rapidly via two pathways: direct adsorption of metabolites on microplastics and bridging interactions mediated by macromolecules. The main eco-corona components were common across all soils and microplastics tested and were identified as lipids and lipid-like molecules, phenylpropanoids and polyketides, nucleosides, nucleotides, and their analogues. WESMs were found to reduce the adsorption of co-occurring organic contaminants to microplastics by two pathways: reduced adsorption to the eco-corona surface and co-solubilization in the surrounding water. These impacts from the eco-corona and the soil metabolome should be considered within fate and risk assessments of microplastics and co-occurring contaminants." @default.
- W4376872279 created "2023-05-18" @default.
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- W4376872279 date "2023-05-17" @default.
- W4376872279 modified "2023-10-01" @default.
- W4376872279 title "Soil Metabolome Impacts the Formation of the Eco-corona and Adsorption Processes on Microplastic Surfaces" @default.
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- W4376872279 doi "https://doi.org/10.1021/acs.est.3c01877" @default.
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