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• W4376872698 abstract "Extended transition state-natural orbitals for chemical valence (ETS-NOCV)] data were used to rank electron acceptor capacities for several potentially synergistic anionic ligands incorporated into linear d10 [(NH3)Pd(A)]-, square planar d8 [(NN2)Ru(A)]-, and octahedral d6 [(AsN4)Tc(A)]- complexes [A = anionic ligand, NN2 = HN(CH2CH2CH2NH2)2, and AsN4 = [As(CH2CH2CH2NH2)4]-]. It was possible to differentiate between the best acceptors, among them BI2- and B(CF3)2-, and the poorest ones. A sizable fraction of the anionic ligands studied exhibit similar acceptor capacities (backbonding), mostly regardless of d electron count. A number of trends were discerned, including the fact that acceptor capacity decreases down families and across rows but increases down families of the peripheral substituents. The latter appears tied to the ability of the peripheral ligands to compete with the metal in donating electrons to the ligand-binding atom." @default.
• W4376872698 created "2023-05-18" @default.
• W4376872698 creator A5013496975 @default.
• W4376872698 date "2023-05-17" @default.
• W4376872698 modified "2023-09-27" @default.
• W4376872698 title "π Acceptor Abilities of Anionic Ligands: Comparisons Involving Anionic Ligands Incorporated into Linear <i>d</i>¹⁰ [(NH₃)Pd(A)]⁻, Square Planar <i>d</i>⁸ [(NN₂)Ru(A)]⁻, and Octahedral <i>d</i>⁶ [(AsN₄)Tc(A)]⁻ Complexes" @default.
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• W4376872698 doi "https://doi.org/10.1021/acs.inorgchem.2c03778" @default.
• W4376872698 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37195088" @default.
• W4376872698 hasPublicationYear "2023" @default.
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