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- W4376877271 abstract "Cross-electrophile coupling reactions have evolved into a major strategy for rapidly assembling important molecules, yet challenges remain for the formation of C(sp3)–C(sp3) bonds that form the core of nearly all organic compounds. Herein, we report a distinct, transition metal-free platform to form such bonds without the need for activating or stabilizing groups on the coupling partners. The reaction is enabled by an unusual single electron transfer in a frustrated ion pair and is complementary in terms of scope to transition metal-catalyzed processes. Moreover, we could further leverage this new mechanistic manifold in the design of other reactions, showing the broad potential of this new reactivity in organic synthesis." @default.
- W4376877271 created "2023-05-18" @default.
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- W4376877271 date "2023-05-17" @default.
- W4376877271 modified "2023-09-29" @default.
- W4376877271 title "Frustrated Ion Pair-Enabled Cross-Electrophile Coupling of Unactivated Alkyl Electrophiles" @default.
- W4376877271 doi "https://doi.org/10.26434/chemrxiv-2023-q2gdd" @default.
- W4376877271 hasPublicationYear "2023" @default.
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