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- W4377010462 abstract "The synthesis of sterically demanding 2,6-bis(2,4,6-trimethylphenyl)phenyl (Ter)-stabilized and H-substituted diphosphanes TerHP–PR2 (4a–4c) via conversion of the phosphide TerPHK (2) with secondary chlorophosphanes ClPR2 (3a–3c, where R = iPr, Ph, and tBu, respectively) is described. The diphosphanes 4a–4c were deprotonated using KH in tetrahydrofuran, selectively yielding the potassium phosphinophosphides K[TerP–PR2] (5a–5c). These phosphinophosphides are stable in solution as well as in the solid state and can be further functionalized via salt-metathesis reactions. Reaction with organosilyl halides selectively yields the silylated diphosphanes Ter(SiR12R2)P–P(iPr)2 (6a and 6b, where R1 = R2 = CH3 and R1 = CH3, R2 = Ph, respectively), whereas conversion with chlorophosphanes selectively yields the triphosphanes R12P–P(Ter)–P(iPr)2 (7a and 7b, where R = iPr and Ph, respectively)." @default.
- W4377010462 created "2023-05-19" @default.
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- W4377010462 creator A5047427644 @default.
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- W4377010462 date "2023-05-18" @default.
- W4377010462 modified "2023-09-29" @default.
- W4377010462 title "Synthesis of Stable Potassium Phosphinophosphides and Reaction with Organosilyl Halides and Chlorophosphanes" @default.
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- W4377010462 doi "https://doi.org/10.1021/acs.inorgchem.3c00950" @default.
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