Matches in SemOpenAlex for { <https://semopenalex.org/work/W4377011290> ?p ?o ?g. }
- W4377011290 endingPage "11836" @default.
- W4377011290 startingPage "11829" @default.
- W4377011290 abstract "In the electrochemical CO2 reduction reaction (CO2RR), CO2 activation is always the first step, followed by the subsequent hydrogenation. The catalytic performance of CO2RR is intrinsically restricted by the competition between molecular CO2 activation and CO2 reduction product release. Here, we design a heteronuclear Fe1-Mo1 dual-metal catalytic pair on ordered porous carbon that features a high catalytic performance for driving electrochemical CO2 reduction to CO. Combining real-time near-ambient pressure X-ray photoelectron spectroscopy, operando 57Fe Mössbauer spectroscopy, and in situ attenuated total reflectance surface-enhanced infrared absorption spectroscopy measurements with density functional theory calculations, chemical adsorption of CO2 is observed on the Fe1-Mo1 catalytic pair through a bridge configuration, which prompts the bending of the CO2 molecule for CO2 activation and then facilitates the subsequent hydrogeneration reaction. More importantly, the dynamic adsorption configuration transition from the bridge configuration of CO2 on Fe1-Mo1 to the linear configuration of CO on the Fe1 center results in breaking the scaling relationship in CO2RR, simultaneously promoting the CO2 activation and the CO release." @default.
- W4377011290 created "2023-05-19" @default.
- W4377011290 creator A5006059514 @default.
- W4377011290 creator A5011568766 @default.
- W4377011290 creator A5013402262 @default.
- W4377011290 creator A5013434268 @default.
- W4377011290 creator A5018932156 @default.
- W4377011290 creator A5024741363 @default.
- W4377011290 creator A5037527518 @default.
- W4377011290 creator A5037989489 @default.
- W4377011290 creator A5048943499 @default.
- W4377011290 creator A5052244533 @default.
- W4377011290 creator A5054330732 @default.
- W4377011290 creator A5059627859 @default.
- W4377011290 creator A5064684366 @default.
- W4377011290 creator A5065231573 @default.
- W4377011290 creator A5091970973 @default.
- W4377011290 date "2023-05-18" @default.
- W4377011290 modified "2023-10-14" @default.
- W4377011290 title "Circumventing CO<sub>2</sub> Reduction Scaling Relations Over the Heteronuclear Diatomic Catalytic Pair" @default.
- W4377011290 cites W2268456782 @default.
- W4377011290 cites W2276596429 @default.
- W4377011290 cites W2318713233 @default.
- W4377011290 cites W2330369522 @default.
- W4377011290 cites W2736999751 @default.
- W4377011290 cites W2750939294 @default.
- W4377011290 cites W2767138048 @default.
- W4377011290 cites W2779952271 @default.
- W4377011290 cites W2790507915 @default.
- W4377011290 cites W2899283097 @default.
- W4377011290 cites W2903365446 @default.
- W4377011290 cites W2909429646 @default.
- W4377011290 cites W2933816311 @default.
- W4377011290 cites W2949697738 @default.
- W4377011290 cites W3006891031 @default.
- W4377011290 cites W3012441403 @default.
- W4377011290 cites W3025104221 @default.
- W4377011290 cites W3046651813 @default.
- W4377011290 cites W3084901341 @default.
- W4377011290 cites W3103953151 @default.
- W4377011290 cites W3110343376 @default.
- W4377011290 cites W3113208759 @default.
- W4377011290 cites W3127284151 @default.
- W4377011290 cites W3160603623 @default.
- W4377011290 cites W3173882296 @default.
- W4377011290 cites W3175322153 @default.
- W4377011290 cites W3197897100 @default.
- W4377011290 cites W3206375149 @default.
- W4377011290 cites W3215729223 @default.
- W4377011290 cites W4200170750 @default.
- W4377011290 cites W4225108171 @default.
- W4377011290 cites W4225523429 @default.
- W4377011290 cites W4229061364 @default.
- W4377011290 cites W4250085753 @default.
- W4377011290 cites W4283388994 @default.
- W4377011290 cites W4289784883 @default.
- W4377011290 cites W4304698171 @default.
- W4377011290 cites W4376596313 @default.
- W4377011290 doi "https://doi.org/10.1021/jacs.3c03426" @default.
- W4377011290 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37199388" @default.
- W4377011290 hasPublicationYear "2023" @default.
- W4377011290 type Work @default.
- W4377011290 citedByCount "4" @default.
- W4377011290 countsByYear W43770112902023 @default.
- W4377011290 crossrefType "journal-article" @default.
- W4377011290 hasAuthorship W4377011290A5006059514 @default.
- W4377011290 hasAuthorship W4377011290A5011568766 @default.
- W4377011290 hasAuthorship W4377011290A5013402262 @default.
- W4377011290 hasAuthorship W4377011290A5013434268 @default.
- W4377011290 hasAuthorship W4377011290A5018932156 @default.
- W4377011290 hasAuthorship W4377011290A5024741363 @default.
- W4377011290 hasAuthorship W4377011290A5037527518 @default.
- W4377011290 hasAuthorship W4377011290A5037989489 @default.
- W4377011290 hasAuthorship W4377011290A5048943499 @default.
- W4377011290 hasAuthorship W4377011290A5052244533 @default.
- W4377011290 hasAuthorship W4377011290A5054330732 @default.
- W4377011290 hasAuthorship W4377011290A5059627859 @default.
- W4377011290 hasAuthorship W4377011290A5064684366 @default.
- W4377011290 hasAuthorship W4377011290A5065231573 @default.
- W4377011290 hasAuthorship W4377011290A5091970973 @default.
- W4377011290 hasConcept C119824511 @default.
- W4377011290 hasConcept C121332964 @default.
- W4377011290 hasConcept C147789679 @default.
- W4377011290 hasConcept C150394285 @default.
- W4377011290 hasConcept C161790260 @default.
- W4377011290 hasConcept C17525397 @default.
- W4377011290 hasConcept C178790620 @default.
- W4377011290 hasConcept C179104552 @default.
- W4377011290 hasConcept C185592680 @default.
- W4377011290 hasConcept C32909587 @default.
- W4377011290 hasConcept C52859227 @default.
- W4377011290 hasConcept C55904794 @default.
- W4377011290 hasConcept C62520636 @default.
- W4377011290 hasConcept C92381491 @default.
- W4377011290 hasConceptScore W4377011290C119824511 @default.
- W4377011290 hasConceptScore W4377011290C121332964 @default.
- W4377011290 hasConceptScore W4377011290C147789679 @default.
- W4377011290 hasConceptScore W4377011290C150394285 @default.