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- W4377012830 endingPage "1892" @default.
- W4377012830 startingPage "1883" @default.
- W4377012830 abstract "Abstract The photocatalytic Meerwein arylation between aromatic diazonium salts and isopropenyl acetate under blue LED light irradiation in aqueous medium has been deeply investigated. Optimization of the reaction conditions in terms of substrate concentration, ester equivalents, cosolvent type and amount, reaction time and photocatalyst source, has allowed the access to a variety of 1‐arylpropan‐2‐ones with yields up to 95% using 9‐mesityl‐10‐methylacridinium perchlorate ([Acr‐Mes]ClO 4 ). Next, the design of a one‐pot sequential photobiocatalytic linear approach was accomplished, by the combination of the Meerwein arylation with the bioreduction of the corresponding ketone intermediates. Thus, a total of 19 pairs of 1‐arylpropan‐2‐ol enantiomers were obtained depending on the alcohol dehydrogenase stereopreference. Global yields up to 76% were attained with high to excellent stereoselectivity (90 to >99% ee ). Also, it was possible to get access to both 1‐phenylpropan‐2‐ol antipodes (51–53% yield) starting from aniline through a one‐pot three‐step sequential photobiocatalytic protocol." @default.
- W4377012830 created "2023-05-19" @default.
- W4377012830 creator A5014741218 @default.
- W4377012830 creator A5026962998 @default.
- W4377012830 creator A5039735512 @default.
- W4377012830 creator A5090958261 @default.
- W4377012830 date "2023-05-31" @default.
- W4377012830 modified "2023-10-02" @default.
- W4377012830 title "From Diazonium Salts to Optically Active 1‐Arylpropan‐2‐ols Through a Sequential Photobiocatalytic Approach" @default.
- W4377012830 cites W1621611245 @default.
- W4377012830 cites W1927042373 @default.
- W4377012830 cites W1970623750 @default.
- W4377012830 cites W1977748987 @default.
- W4377012830 cites W1994702118 @default.
- W4377012830 cites W1996924542 @default.
- W4377012830 cites W2014393856 @default.
- W4377012830 cites W2020706111 @default.
- W4377012830 cites W2021953365 @default.
- W4377012830 cites W2030472449 @default.
- W4377012830 cites W2032368646 @default.
- W4377012830 cites W2051822378 @default.
- W4377012830 cites W2057273219 @default.
- W4377012830 cites W2059552139 @default.
- W4377012830 cites W2075393372 @default.
- W4377012830 cites W2090490503 @default.
- W4377012830 cites W2091949042 @default.
- W4377012830 cites W2120612310 @default.
- W4377012830 cites W2149935222 @default.
- W4377012830 cites W2152940535 @default.
- W4377012830 cites W2159423122 @default.
- W4377012830 cites W2161143297 @default.
- W4377012830 cites W2294124714 @default.
- W4377012830 cites W2321459842 @default.
- W4377012830 cites W2342772717 @default.
- W4377012830 cites W2343778131 @default.
- W4377012830 cites W2405760312 @default.
- W4377012830 cites W2474130324 @default.
- W4377012830 cites W2498949635 @default.
- W4377012830 cites W2529819049 @default.
- W4377012830 cites W2563407901 @default.
- W4377012830 cites W2621094641 @default.
- W4377012830 cites W2751743037 @default.
- W4377012830 cites W2772019402 @default.
- W4377012830 cites W2781766538 @default.
- W4377012830 cites W2783336705 @default.
- W4377012830 cites W2783485942 @default.
- W4377012830 cites W2786883988 @default.
- W4377012830 cites W2800593603 @default.
- W4377012830 cites W2804258724 @default.
- W4377012830 cites W2804699682 @default.
- W4377012830 cites W2808179173 @default.
- W4377012830 cites W2808613462 @default.
- W4377012830 cites W2810064825 @default.
- W4377012830 cites W2886479683 @default.
- W4377012830 cites W2895821662 @default.
- W4377012830 cites W2901606026 @default.
- W4377012830 cites W2909751444 @default.
- W4377012830 cites W2921942686 @default.
- W4377012830 cites W2936378241 @default.
- W4377012830 cites W2944948325 @default.
- W4377012830 cites W2952048176 @default.
- W4377012830 cites W2971965824 @default.
- W4377012830 cites W2994708032 @default.
- W4377012830 cites W2999979503 @default.
- W4377012830 cites W3016545710 @default.
- W4377012830 cites W3021424812 @default.
- W4377012830 cites W3034798550 @default.
- W4377012830 cites W3036039214 @default.
- W4377012830 cites W3045553420 @default.
- W4377012830 cites W3080845583 @default.
- W4377012830 cites W3086436553 @default.
- W4377012830 cites W3088798280 @default.
- W4377012830 cites W3089215994 @default.
- W4377012830 cites W3112071470 @default.
- W4377012830 cites W3112486055 @default.
- W4377012830 cites W3113186816 @default.
- W4377012830 cites W3117727393 @default.
- W4377012830 cites W3125283706 @default.
- W4377012830 cites W3128697690 @default.
- W4377012830 cites W3129702168 @default.
- W4377012830 cites W3131851365 @default.
- W4377012830 cites W3145243805 @default.
- W4377012830 cites W3157899512 @default.
- W4377012830 cites W3163489256 @default.
- W4377012830 cites W3174090405 @default.
- W4377012830 cites W3179946079 @default.
- W4377012830 cites W3188705123 @default.
- W4377012830 cites W3194086816 @default.
- W4377012830 cites W3200587670 @default.
- W4377012830 cites W3212204911 @default.
- W4377012830 cites W4210665919 @default.
- W4377012830 cites W4214833985 @default.
- W4377012830 cites W4220969851 @default.
- W4377012830 cites W4224054741 @default.
- W4377012830 cites W4226317020 @default.
- W4377012830 cites W4240478808 @default.
- W4377012830 cites W4241230574 @default.
- W4377012830 cites W4285993182 @default.