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• W4377013192 endingPage "567" @default.
• W4377013192 startingPage "555" @default.
• W4377013192 abstract "The most atom-efficient synthetic method for N-unprotected ketimines (N-H ketimines) from ketones is the dehydration condensation reaction with ammonia (NH3). However, until now, few synthetic methods for N-H ketimines with high versatility have been known. In this study, we examined various solid acids and found that N-H diaryl ketimines with various functional groups on the aryl groups could be synthesized in high yields from diaryl ketones and NH3 under solvent-free conditions using silica-alumina (SiO2-Al2O3) or proton-exchanged Y-type zeolite (H-Y). Solid-state 13C and 15N NMR measurements indicated that the N-H ketimine formed in the pores of acidic zeolite was coordinated to NH4+ species on the pore surface. By quantum chemical calculations we also discussed the reason why the dehydration-condensation reaction between ketone and NH3, which is an endothermic reaction in a vacuum, was biased toward the product side in the actual experiment. In addition, this synthetic method can be applied to synthesize N-H alkyl ketimines with α-acidic hydrogens, which are less stable and more sensitive to hydrolysis and oligomerization than diaryl ketimines. We discovered that N-H diaryl ketimines with various functional groups on the aryl groups were able to synthesize in high yields from the diaryl ketones and NH3 under solvent-free conditions using silica-alumina (SiO2-Al2O3) or proton-exchanged Y-type zeolite (H-Y). In addition, this synthetic method can be applied to synthesize more labile N-H alkyl ketimines with α-acidic hydrogens." @default.
• W4377013192 created "2023-05-19" @default.
• W4377013192 creator A5009783017 @default.
• W4377013192 creator A5012129134 @default.
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• W4377013192 date "2023-06-15" @default.
• W4377013192 modified "2023-10-02" @default.
• W4377013192 title "Synthesis of <i>N</i>-Unprotected Diaryl Ketimines and Alkyl Ketimines from Ketones and Ammonia Using Porous Solid Acids with Analysis of Their Adsorption Behavior" @default.
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