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• W4377013909 endingPage "075008" @default.
• W4377013909 startingPage "075008" @default.
• W4377013909 abstract "Abstract Atmospheric pressure metal–organic chemical vapour deposition was used to synthesize Ag-containing ZnO nanostructures of different morphology on Si substrates coated by Ag. Ag from Ag/Si substrates and Ag from silver acetylacetonate after its decomposition were used as a catalyst for ZnO nanocrystal growth for deposition of ZnO nanostructures with different morphologies. We investigated the relation of the structural parameters and chemical composition probed by x-ray diffraction (XRD), x-ray photoelectron spectroscopy (XPS), and Raman spectroscopy with the photoluminescence (PL) properties and electron–phonon coupling (EPC) reflected in the multi-phonon Raman spectra. The Raman and PL spectra were studied at different powers of the exciting laser radiation ( P exc ). The spectral position and width of the phonon Raman peaks and the near bandgap PL band at low P exc are supposed to be determined by the structural quality of the surfaces/boundaries of the crystallites. The intensity of the near-bandgap and defect-related PL and the magnitude of the EPC are additionally affected by the dopant concentration. Because of the large crystallite size (>30 nm, determined from XRD), the effects of phonon or electron confinement are negligible in these nanostructures. The behaviour of the position and width of phonon and PL bands with increasing P exc indicates that the heat dissipation in the film, which is dependent on the nanostructure morphology and Ag content, plays an important role. In addition, the cytotoxicity of ZnO:Ag nanostructures was investigated by using monolayer cell cultures of epithelioid origin Madin-Darby bovine kidney and Madin-Darby canine kidney cells at a MTT assay revealing that the level of silver doping of ZnO nanostructures, their morphology, and geometric dimensions determine their toxic effects." @default.
• W4377013909 created "2023-05-19" @default.
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• W4377013909 date "2023-05-30" @default.
• W4377013909 modified "2023-10-14" @default.
• W4377013909 title "The effect of Ag doping on the structure, optical, and electronic properties of ZnO nanostructures deposited by atmospheric pressure MOCVD on Ag/Si substrates" @default.
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• W4377013909 doi "https://doi.org/10.1088/1361-6641/acd6b2" @default.
• W4377013909 hasPublicationYear "2023" @default.
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