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- W4377016094 abstract "Complexation with strong competitors (i.e., Ba2+, Ca2+, and K+) shortens the length of the chromophore in bis-aza-18-crown-6-containing dienones of 2,4-dibenzylenecyclo-butanone series due to the weakening of π–LP conjugation as well as disruption of the quinonoid structure in the ground state of the dye (LP is the lone electron pair of the crown nitrogen atom). In the excited state, recoordination of metal cations in the crown cavity takes place. The complexation as well as the newly discovered photorecoordination in these metal complexes may be used to control the chromophore properties of the samples." @default.
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- W4377016094 date "2023-05-01" @default.
- W4377016094 modified "2023-10-18" @default.
- W4377016094 title "Photoinduced recoordination in the complexes of bis-aza-18-crown-6-containing dibenzylidenecyclobutanone with alkali and alkaline-earth metal cations" @default.
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- W4377016094 doi "https://doi.org/10.1016/j.mencom.2023.04.026" @default.
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