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• W4377018838 endingPage "1537" @default.
• W4377018838 startingPage "1525" @default.
• W4377018838 abstract "Reduction of CO2 with catecholborane (HBcat) is known to be catalyzed by nickel hydride complexes supported by a bis(phosphinite)-based or POCOP-type pincer ligand. The objective of this research is to examine how changing the metal center from nickel to palladium would impact the outcome of CO2 reduction. Stoichiometric studies show that the palladium hydride complexes react rapidly with CO2, although the resulting palladium formate complexes can lose CO2 under reduced pressure or in chloroform. In the presence of HBcat, the formate complexes are converted back to the palladium hydride species while the formate group is reduced to CH3OBcat. This process is also accompanied by the formation of palladium bis(catecholato)borate complexes, which diverts some of the HBcat to yield B2(cat)3 and B2H6. For palladium hydrides stabilized by a POCOP-pincer ligand with relatively small phosphorus substituents (e.g., isopropyl or cyclopentyl groups), HBcat cleaves the P–O bonds in the ligand backbone to degrade the catalysts to secondary phosphine complexes. Without CO2, HBcat also undergoes H2 elimination with the Pd–H moiety to form palladium boryl complexes. These side reactions with HBcat and the palladium pincer complexes play profound roles in the catalytic reduction of CO2 with the borane." @default.
• W4377018838 created "2023-05-19" @default.
• W4377018838 creator A5009586955 @default.
• W4377018838 creator A5009651035 @default.
• W4377018838 creator A5036175953 @default.
• W4377018838 creator A5040305041 @default.
• W4377018838 creator A5062126454 @default.
• W4377018838 creator A5076262237 @default.
• W4377018838 date "2023-05-18" @default.
• W4377018838 modified "2023-09-27" @default.
• W4377018838 title "Pitfalls for POCOP-Type Palladium Pincer Complexes in Catalytic Reduction of CO₂ with Catecholborane" @default.
• W4377018838 cites W1005988859 @default.
• W4377018838 cites W1870760280 @default.
• W4377018838 cites W1925043246 @default.
• W4377018838 cites W1950193035 @default.
• W4377018838 cites W1968218438 @default.
• W4377018838 cites W1973111883 @default.
• W4377018838 cites W1974168395 @default.
• W4377018838 cites W1974204053 @default.
• W4377018838 cites W1978594687 @default.
• W4377018838 cites W1980089423 @default.
• W4377018838 cites W1980536158 @default.
• W4377018838 cites W1992591486 @default.
• W4377018838 cites W1997503806 @default.
• W4377018838 cites W1998085580 @default.
• W4377018838 cites W1998811239 @default.
• W4377018838 cites W2006420601 @default.
• W4377018838 cites W2007033049 @default.
• W4377018838 cites W2009997593 @default.
• W4377018838 cites W2010832049 @default.
• W4377018838 cites W2017267600 @default.
• W4377018838 cites W2030637995 @default.
• W4377018838 cites W2033923150 @default.
• W4377018838 cites W2035395022 @default.
• W4377018838 cites W2040454689 @default.
• W4377018838 cites W2049353031 @default.
• W4377018838 cites W2051469896 @default.
• W4377018838 cites W2051995155 @default.
• W4377018838 cites W2055418060 @default.
• W4377018838 cites W2070451357 @default.
• W4377018838 cites W2083073868 @default.
• W4377018838 cites W2084863239 @default.
• W4377018838 cites W2086251563 @default.
• W4377018838 cites W2089307567 @default.
• W4377018838 cites W2092237206 @default.
• W4377018838 cites W2095835074 @default.
• W4377018838 cites W2105000835 @default.
• W4377018838 cites W2108812250 @default.
• W4377018838 cites W2117276502 @default.
• W4377018838 cites W2120712436 @default.
• W4377018838 cites W2124644556 @default.
• W4377018838 cites W2126688530 @default.
• W4377018838 cites W2127362721 @default.
• W4377018838 cites W2133156121 @default.
• W4377018838 cites W2140141423 @default.
• W4377018838 cites W2161016503 @default.
• W4377018838 cites W2161435135 @default.
• W4377018838 cites W2168809728 @default.
• W4377018838 cites W2274349515 @default.
• W4377018838 cites W2274366216 @default.
• W4377018838 cites W2296880544 @default.
• W4377018838 cites W2312280253 @default.
• W4377018838 cites W2313559347 @default.
• W4377018838 cites W2313919682 @default.
• W4377018838 cites W2314598551 @default.
• W4377018838 cites W2319324021 @default.
• W4377018838 cites W2319735561 @default.
• W4377018838 cites W2321016781 @default.
• W4377018838 cites W2321291366 @default.
• W4377018838 cites W2322680748 @default.
• W4377018838 cites W2324586646 @default.
• W4377018838 cites W2325800243 @default.
• W4377018838 cites W2327303995 @default.
• W4377018838 cites W2328568239 @default.
• W4377018838 cites W2332955151 @default.
• W4377018838 cites W2335116514 @default.
• W4377018838 cites W2379619782 @default.
• W4377018838 cites W2399101729 @default.
• W4377018838 cites W2462270930 @default.
• W4377018838 cites W2507764024 @default.
• W4377018838 cites W2511123279 @default.
• W4377018838 cites W2513011499 @default.
• W4377018838 cites W2514137042 @default.
• W4377018838 cites W2530384996 @default.
• W4377018838 cites W2539744650 @default.
• W4377018838 cites W2555004973 @default.
• W4377018838 cites W2555560179 @default.
• W4377018838 cites W2577366206 @default.
• W4377018838 cites W2579130002 @default.
• W4377018838 cites W2582824092 @default.
• W4377018838 cites W2588907351 @default.
• W4377018838 cites W2591718948 @default.
• W4377018838 cites W2596142038 @default.
• W4377018838 cites W2607090104 @default.
• W4377018838 cites W2619340847 @default.
• W4377018838 cites W2747030391 @default.
• W4377018838 cites W2755269103 @default.
• W4377018838 cites W2757964270 @default.

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