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- W4377077185 abstract "Gold forms rings: AuCl-catalyzed cyclization of (α-alkoxy alkyl) (ortho-alkynyl phenyl) sulfides 1 proceeds under mild conditions to give 3-(α-alkoxy alkyl) benzothiophenes 2 in high yields for a wide range of substrates (see scheme). The starting materials are readily available through acetalization of ortho-bromobenzenethiol and subsequent Sonogashira coupling. This methodology provides an atom-economic route to sulfur-containing heteroarenes." @default.
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- W4377077185 date "2006-06-28" @default.
- W4377077185 modified "2023-10-17" @default.
- W4377077185 title "Gold-Catalyzed Intramolecular Carbothiolation of Alkynes: Synthesis of 2,3-Disubstituted Benzothiophenes from (α-Alkoxy Alkyl) (ortho-Alkynyl Phenyl) Sulfides" @default.
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- W4377077185 doi "https://doi.org/10.1002/anie.200601178" @default.
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