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- W4377088227 abstract "Dihydropyridines are versatile building blocks for the synthesis of pyridines, tetrahydropyridines, and piperidines. Addition of nucleophiles to activated pyridinium salts allows synthesis of 1,2-, 1,4-, or 1,6-dihydropyridines; however, this process often leads to a mixture of constitutional isomers. Catalyst-controlled regioselective addition of nucleophiles to pyridiniums has the potential to solve this problem. Herein, we report that the regioselective addition of boron-based nucleophiles to pyridinium salts can be accomplished by the choice of a Rh catalyst." @default.
- W4377088227 created "2023-05-20" @default.
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- W4377088227 date "2023-05-19" @default.
- W4377088227 modified "2023-10-18" @default.
- W4377088227 title "Catalyst-Controlled Enantioselective and Regiodivergent Addition of Aryl Boron Nucleophiles to N-Alkyl Nicotinate Salts" @default.
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- W4377088227 doi "https://doi.org/10.1021/jacs.3c03048" @default.
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