FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4377089127> ?p ?o ?g. }

• W4377089127 endingPage "102914" @default.
• W4377089127 startingPage "102914" @default.
• W4377089127 abstract "Oxovanadium (IV) bis-Schiff base complex was synthesized by a facile complexation of 2 molar ratio of 2‑hydroxy-Schiff base ligand (HL) with 1 molar ratio of VO2+ ion giving mononuclear VOL2 complex with a square pyramidal geometry. The structure conformation of HL and its corresponding VOL2 complex was assigned within various spectroscopic tools (IR, UV–vis. Mass spectra), as well as the elemental analyses (EA). The deprotonated 4-OH group in VOL2 caused a successful coating of VOL2 on a mixed oxides of TiO2–ZnO nanoparticles awarding nanocomposite of TiO2–ZnO@VOL2. By applying alternative analytical techniques, the surface morphology and internal structure TiO2–ZnO@VOL2 nanocomposites were investigated compared to that of TiO2–ZnO, i.e. by XRD, FESEM, HR-TEM, EDS and IR spectra), and also with TGA and BET (adsorption–desorption isotherm). The catalytic effectiveness of both homogeneous and heterogeneous catalysts (VOL2 and TiO2–ZnO@VOL2) was examined in the productive oxygenation reactions of BA (benzyl alcohol) by an aqueous hydrogen peroxide under an aerobic environment to the chemo-selective product benzaldehyde (BZ), and benzoic acid (BO), as the overodixation product. Both VOL2 and TiO2-ZnO@VOL2 catalysts exhibited obvious classified action by 89% and 91% yielding amount of benzaldehyde after 4 h for reaction temperature 80 and 90 °C, respectively. The differentiation between them in the catalytic reactivity was depending on the heterogeneity and the effect of the coated TiO2–ZnO nanoparticles on the VOL2 catalytic potential. The kinetic parameter of the productive redox protocols for both catalyst was examined. Additionally, some other cyclic and acyclic alcohols were exhibited the productive redox protocol in the optimum control of both catalysts." @default.
• W4377089127 created "2023-05-20" @default.
• W4377089127 creator A5026249864 @default.
• W4377089127 creator A5034798627 @default.
• W4377089127 creator A5054284593 @default.
• W4377089127 creator A5075113262 @default.
• W4377089127 creator A5086972812 @default.
• W4377089127 creator A5089520590 @default.
• W4377089127 date "2023-07-01" @default.
• W4377089127 modified "2023-09-23" @default.
• W4377089127 title "Facile synthetic route of TiO2–ZnO heteronanostructure coated by oxovanadium (IV) bis-Schiff base complex as a potential effective homogeneous/heterogeneous catalysts for alcohols redox systems" @default.
• W4377089127 cites W1878648830 @default.
• W4377089127 cites W1964613683 @default.
• W4377089127 cites W1980972092 @default.
• W4377089127 cites W1989692874 @default.
• W4377089127 cites W2004445562 @default.
• W4377089127 cites W2011254969 @default.
• W4377089127 cites W2014099170 @default.
• W4377089127 cites W2015864415 @default.
• W4377089127 cites W2017992070 @default.
• W4377089127 cites W2018339315 @default.
• W4377089127 cites W2018341693 @default.
• W4377089127 cites W2019072197 @default.
• W4377089127 cites W2021040320 @default.
• W4377089127 cites W2032848988 @default.
• W4377089127 cites W2042650256 @default.
• W4377089127 cites W2049474126 @default.
• W4377089127 cites W2058313208 @default.
• W4377089127 cites W2064139903 @default.
• W4377089127 cites W2084261777 @default.
• W4377089127 cites W2085023746 @default.
• W4377089127 cites W2146242081 @default.
• W4377089127 cites W2158341036 @default.
• W4377089127 cites W2174167594 @default.
• W4377089127 cites W2175665547 @default.
• W4377089127 cites W2314837838 @default.
• W4377089127 cites W2329313115 @default.
• W4377089127 cites W2513905622 @default.
• W4377089127 cites W2522663057 @default.
• W4377089127 cites W2545230066 @default.
• W4377089127 cites W2595353668 @default.
• W4377089127 cites W2624525329 @default.
• W4377089127 cites W2707425439 @default.
• W4377089127 cites W2734373636 @default.
• W4377089127 cites W2762736103 @default.
• W4377089127 cites W2767275809 @default.
• W4377089127 cites W2767645194 @default.
• W4377089127 cites W2782745861 @default.
• W4377089127 cites W2784327893 @default.
• W4377089127 cites W2790528378 @default.
• W4377089127 cites W2790794217 @default.
• W4377089127 cites W2791646060 @default.
• W4377089127 cites W2794490353 @default.
• W4377089127 cites W2796657947 @default.
• W4377089127 cites W2803737691 @default.
• W4377089127 cites W2805917343 @default.
• W4377089127 cites W2808474578 @default.
• W4377089127 cites W2888958773 @default.
• W4377089127 cites W2888975899 @default.
• W4377089127 cites W2899246795 @default.
• W4377089127 cites W2899721320 @default.
• W4377089127 cites W2900576331 @default.
• W4377089127 cites W2923109768 @default.
• W4377089127 cites W2945918452 @default.
• W4377089127 cites W3001634620 @default.
• W4377089127 cites W3010748278 @default.
• W4377089127 cites W3011750402 @default.
• W4377089127 cites W3015477277 @default.
• W4377089127 cites W3030155821 @default.
• W4377089127 cites W3080840002 @default.
• W4377089127 cites W3087367810 @default.
• W4377089127 cites W3093617890 @default.
• W4377089127 cites W3124057666 @default.
• W4377089127 cites W3128519714 @default.
• W4377089127 cites W3160043020 @default.
• W4377089127 cites W3175979570 @default.
• W4377089127 cites W3183100228 @default.
• W4377089127 cites W3189274002 @default.
• W4377089127 cites W3209538421 @default.
• W4377089127 cites W4280505349 @default.
• W4377089127 cites W4281628939 @default.
• W4377089127 cites W4281784039 @default.
• W4377089127 cites W4285733508 @default.
• W4377089127 cites W4291002527 @default.
• W4377089127 cites W4296050468 @default.
• W4377089127 cites W4300861821 @default.
• W4377089127 cites W4321523385 @default.
• W4377089127 cites W4324145883 @default.
• W4377089127 cites W4365812895 @default.
• W4377089127 doi "https://doi.org/10.1016/j.surfin.2023.102914" @default.
• W4377089127 hasPublicationYear "2023" @default.
• W4377089127 type Work @default.
• W4377089127 citedByCount "1" @default.
• W4377089127 crossrefType "journal-article" @default.
• W4377089127 hasAuthorship W4377089127A5026249864 @default.
• W4377089127 hasAuthorship W4377089127A5034798627 @default.
• W4377089127 hasAuthorship W4377089127A5054284593 @default.
• W4377089127 hasAuthorship W4377089127A5075113262 @default.

• next