Matches in SemOpenAlex for { <https://semopenalex.org/work/W4377220942> ?p ?o ?g. }
- W4377220942 abstract "A one-stone, two-bird method to integrate the soft porosity and electrical properties of distinct metal-organic frameworks (MOFs) into a single material involves the design of conductive-on-insulating MOF (cMOF-on-iMOF) heterostructures that allow for direct electrical control. Herein, we report the synthesis of cMOF-on-iMOF heterostructures using a seeded layer-by-layer method, in which the sorptive iMOF core is combined with chemiresistive cMOF shells. The resulting cMOF-on-iMOF heterostructures exhibit enhanced selective sorption of CO2 compared to the pristine iMOF (298 K, 1 bar, S CO2/H2${{_{{rm CO}{_{2}}/{rm H}{_{2}}}}}$ from 15.4 of ZIF-7 to 43.2-152.8). This enhancement is attributed to the porous interface formed by the hybridization of both frameworks at the molecular level. Furthermore, owing to the flexible structure of the iMOF core, the cMOF-on-iMOF heterostructures with semiconductive soft porous interfaces demonstrated high flexibility in sensing and electrical shape memory toward acetone and CO2 . This behavior was observed through the guest-induced structural changes of the iMOF core, as revealed by the operando synchrotron grazing incidence wide-angle X-ray scattering measurements." @default.
- W4377220942 created "2023-05-23" @default.
- W4377220942 creator A5002237078 @default.
- W4377220942 creator A5002274921 @default.
- W4377220942 creator A5003533984 @default.
- W4377220942 creator A5007356128 @default.
- W4377220942 creator A5013736647 @default.
- W4377220942 creator A5022125628 @default.
- W4377220942 creator A5028281315 @default.
- W4377220942 creator A5029498208 @default.
- W4377220942 creator A5035664781 @default.
- W4377220942 creator A5035890737 @default.
- W4377220942 creator A5051175242 @default.
- W4377220942 creator A5054747517 @default.
- W4377220942 creator A5059184799 @default.
- W4377220942 creator A5080159973 @default.
- W4377220942 creator A5091990401 @default.
- W4377220942 date "2023-06-12" @default.
- W4377220942 modified "2023-10-17" @default.
- W4377220942 title "Integrated Soft Porosity and Electrical Properties of Conductive‐on‐Insulating Metal‐Organic Framework Nanocrystals" @default.
- W4377220942 cites W1964323690 @default.
- W4377220942 cites W2007661885 @default.
- W4377220942 cites W2021767761 @default.
- W4377220942 cites W2045016772 @default.
- W4377220942 cites W2055885723 @default.
- W4377220942 cites W2069771769 @default.
- W4377220942 cites W2083356397 @default.
- W4377220942 cites W2084024682 @default.
- W4377220942 cites W2093257054 @default.
- W4377220942 cites W2150860287 @default.
- W4377220942 cites W2260512632 @default.
- W4377220942 cites W2301791937 @default.
- W4377220942 cites W2331078365 @default.
- W4377220942 cites W2604833464 @default.
- W4377220942 cites W2625875261 @default.
- W4377220942 cites W2765446679 @default.
- W4377220942 cites W2890790869 @default.
- W4377220942 cites W2898261008 @default.
- W4377220942 cites W2901212029 @default.
- W4377220942 cites W2907083886 @default.
- W4377220942 cites W2907619868 @default.
- W4377220942 cites W2910810567 @default.
- W4377220942 cites W2914108609 @default.
- W4377220942 cites W2917062263 @default.
- W4377220942 cites W2926130036 @default.
- W4377220942 cites W2932259935 @default.
- W4377220942 cites W2944270707 @default.
- W4377220942 cites W2953845323 @default.
- W4377220942 cites W2965968768 @default.
- W4377220942 cites W2977255676 @default.
- W4377220942 cites W2979611469 @default.
- W4377220942 cites W2979875321 @default.
- W4377220942 cites W2984828872 @default.
- W4377220942 cites W3001604751 @default.
- W4377220942 cites W3015879182 @default.
- W4377220942 cites W3031986631 @default.
- W4377220942 cites W3041446830 @default.
- W4377220942 cites W3045254922 @default.
- W4377220942 cites W3083070298 @default.
- W4377220942 cites W3090491432 @default.
- W4377220942 cites W3101447464 @default.
- W4377220942 cites W3132550343 @default.
- W4377220942 cites W4220940184 @default.
- W4377220942 doi "https://doi.org/10.1002/anie.202303903" @default.
- W4377220942 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37211927" @default.
- W4377220942 hasPublicationYear "2023" @default.
- W4377220942 type Work @default.
- W4377220942 citedByCount "1" @default.
- W4377220942 countsByYear W43772209422023 @default.
- W4377220942 crossrefType "journal-article" @default.
- W4377220942 hasAuthorship W4377220942A5002237078 @default.
- W4377220942 hasAuthorship W4377220942A5002274921 @default.
- W4377220942 hasAuthorship W4377220942A5003533984 @default.
- W4377220942 hasAuthorship W4377220942A5007356128 @default.
- W4377220942 hasAuthorship W4377220942A5013736647 @default.
- W4377220942 hasAuthorship W4377220942A5022125628 @default.
- W4377220942 hasAuthorship W4377220942A5028281315 @default.
- W4377220942 hasAuthorship W4377220942A5029498208 @default.
- W4377220942 hasAuthorship W4377220942A5035664781 @default.
- W4377220942 hasAuthorship W4377220942A5035890737 @default.
- W4377220942 hasAuthorship W4377220942A5051175242 @default.
- W4377220942 hasAuthorship W4377220942A5054747517 @default.
- W4377220942 hasAuthorship W4377220942A5059184799 @default.
- W4377220942 hasAuthorship W4377220942A5080159973 @default.
- W4377220942 hasAuthorship W4377220942A5091990401 @default.
- W4377220942 hasConcept C119599485 @default.
- W4377220942 hasConcept C127413603 @default.
- W4377220942 hasConcept C147789679 @default.
- W4377220942 hasConcept C150394285 @default.
- W4377220942 hasConcept C159985019 @default.
- W4377220942 hasConcept C171250308 @default.
- W4377220942 hasConcept C175854130 @default.
- W4377220942 hasConcept C179366358 @default.
- W4377220942 hasConcept C185592680 @default.
- W4377220942 hasConcept C192562407 @default.
- W4377220942 hasConcept C202374169 @default.
- W4377220942 hasConcept C2779227376 @default.
- W4377220942 hasConcept C42360764 @default.
- W4377220942 hasConcept C49040817 @default.
- W4377220942 hasConcept C58445606 @default.