FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4377264003> ?p ?o ?g. }

• W4377264003 endingPage "215212" @default.
• W4377264003 startingPage "215212" @default.
• W4377264003 abstract "As an important class of solid-state functional materials, nonlinear optical (NLO) crystals have attracted enormous academic and industrial interest due to their unique ability to generate lasers at a variety of inaccessible wavelengths. A promising NLO material must meet several requirements, including noncentrosymmetric structure, a strong second-harmonic generation (SHG) response, sufficient birefringence (Δn), and a wide transparency window. The rarity of noncentrosymmetric structures and the three rigorous yet contradictory performance criteria pose significant challenges for the development of NLO materials with desired properties. Therefore, it is imperative to develop effective strategies to achieve the goal of rational design of NLO candidates. Among many, chemistry-directing substitution from existing prototypes has proven to be a promising and accessible approach. In this Review, our aim is to provide useful insights for the discovery of new NLO materials by highlighting how to implement precise aliovalent chemical substitution tactics targeting B-site cations to design novel functional NLO materials. For this purpose, we chose early d0-transition metal (d0-TM) and gallium cations-based iodates and selenites due to their structural diversity and abundant sources. The B-site cations, d0-TM and gallium ions, have sequentially variable oxidization states from hexavalent to trivalent states, providing an ideal platform for inequivalent substitution. In the first section, we describe the three types of distortion of d0-TM cation-centered octahedra and briefly explain the aliovalent substitution strategy. To differentiate the concept of fundamental building units (FBUs) or basic building units (BBUs), we adopt secondary building units (SBUs) to specifically describe the structural fragments generated by the connections of [MX6] (M = TM or Ga cations, X = O or F ligands) octahedra with iodate or selenite groups. Next, we provide seven sets of examples to meticulously illustrate the precise aliovalent chemical substitution on B-site cations and discuss the crystal structure and functional properties. We also rationally design and predict several new NLO candidates based on the above-mentioned pathways. Finally, we discuss several factors that affect the functional properties of NLO materials." @default.
• W4377264003 created "2023-05-23" @default.
• W4377264003 creator A5054799694 @default.
• W4377264003 creator A5057749291 @default.
• W4377264003 date "2023-09-01" @default.
• W4377264003 modified "2023-10-05" @default.
• W4377264003 title "Advances in aliovalent substitution strategy for the design and synthesis of nonlinear optical materials: d0 transition metal/gallium iodates and selenites" @default.
• W4377264003 cites W1658788002 @default.
• W4377264003 cites W1680415726 @default.
• W4377264003 cites W1965660424 @default.
• W4377264003 cites W1968963172 @default.
• W4377264003 cites W1989028490 @default.
• W4377264003 cites W2006079418 @default.
• W4377264003 cites W2008195100 @default.
• W4377264003 cites W2015894699 @default.
• W4377264003 cites W2017413978 @default.
• W4377264003 cites W2028173241 @default.
• W4377264003 cites W2047263344 @default.
• W4377264003 cites W2047610226 @default.
• W4377264003 cites W2049736146 @default.
• W4377264003 cites W2050084550 @default.
• W4377264003 cites W2062784615 @default.
• W4377264003 cites W2079712714 @default.
• W4377264003 cites W2084620778 @default.
• W4377264003 cites W2092199939 @default.
• W4377264003 cites W2093867646 @default.
• W4377264003 cites W2107141326 @default.
• W4377264003 cites W2159921116 @default.
• W4377264003 cites W2166586090 @default.
• W4377264003 cites W2283575573 @default.
• W4377264003 cites W2323704540 @default.
• W4377264003 cites W2334843210 @default.
• W4377264003 cites W2505742090 @default.
• W4377264003 cites W2556254339 @default.
• W4377264003 cites W2561103969 @default.
• W4377264003 cites W2602939084 @default.
• W4377264003 cites W2609684095 @default.
• W4377264003 cites W2739026302 @default.
• W4377264003 cites W2770765626 @default.
• W4377264003 cites W2791371525 @default.
• W4377264003 cites W2807959660 @default.
• W4377264003 cites W2902135449 @default.
• W4377264003 cites W2907070987 @default.
• W4377264003 cites W2909130943 @default.
• W4377264003 cites W2916098729 @default.
• W4377264003 cites W2949219860 @default.
• W4377264003 cites W2950278028 @default.
• W4377264003 cites W2950348207 @default.
• W4377264003 cites W2950753222 @default.
• W4377264003 cites W2981254977 @default.
• W4377264003 cites W2985648842 @default.
• W4377264003 cites W2990128662 @default.
• W4377264003 cites W2995904655 @default.
• W4377264003 cites W3004742386 @default.
• W4377264003 cites W3022973919 @default.
• W4377264003 cites W3037791944 @default.
• W4377264003 cites W3042223058 @default.
• W4377264003 cites W3045366844 @default.
• W4377264003 cites W3081319616 @default.
• W4377264003 cites W3111165386 @default.
• W4377264003 cites W3138909610 @default.
• W4377264003 cites W3164230548 @default.
• W4377264003 cites W3165316347 @default.
• W4377264003 cites W3171862096 @default.
• W4377264003 cites W3173281143 @default.
• W4377264003 cites W3191543334 @default.
• W4377264003 cites W3202122179 @default.
• W4377264003 cites W4250105254 @default.
• W4377264003 cites W4254286119 @default.
• W4377264003 cites W4283326964 @default.
• W4377264003 cites W4288063158 @default.
• W4377264003 cites W4288520733 @default.
• W4377264003 cites W4306842422 @default.
• W4377264003 cites W4315709560 @default.
• W4377264003 cites W4318205575 @default.
• W4377264003 doi "https://doi.org/10.1016/j.ccr.2023.215212" @default.
• W4377264003 hasPublicationYear "2023" @default.
• W4377264003 type Work @default.
• W4377264003 citedByCount "1" @default.
• W4377264003 countsByYear W43772640032023 @default.
• W4377264003 crossrefType "journal-article" @default.
• W4377264003 hasAuthorship W4377264003A5054799694 @default.
• W4377264003 hasAuthorship W4377264003A5057749291 @default.
• W4377264003 hasBestOaLocation W43772640031 @default.
• W4377264003 hasConcept C106773901 @default.
• W4377264003 hasConcept C115624301 @default.
• W4377264003 hasConcept C121332964 @default.
• W4377264003 hasConcept C147789679 @default.
• W4377264003 hasConcept C150394285 @default.
• W4377264003 hasConcept C158622935 @default.
• W4377264003 hasConcept C161790260 @default.
• W4377264003 hasConcept C171250308 @default.
• W4377264003 hasConcept C178790620 @default.
• W4377264003 hasConcept C179366358 @default.
• W4377264003 hasConcept C185592680 @default.
• W4377264003 hasConcept C192562407 @default.
• W4377264003 hasConcept C198819137 @default.
• W4377264003 hasConcept C199360897 @default.

• next