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- W4377291710 abstract "Abstract As a key component of lithium‐ion batteries (LIBs), separator plays a crucial role in the performance and safety of LIBs. In this paper, a cellulose‐based porous membrane modified by nano CaCO 3 is prepared conveniently by electrospinning. The membrane exhibits rich fibrous porous networks and uniform distribution of nanoparticles. Strengthened by CaCO 3 , the tensile strength of the cellulose porous membrane elevates from 4.7 ± 0.4 MPa to 7.7 ± 0.7 MPa. Besides, the modified membranes possess improved thermal stability and can maintain their original size after treatment at 150°C and 180°C. Also, the electrolyte uptake of cellulose/CaCO 3 membrane is 73% higher than that of the pure cellulose membrane. Thus, the ionic conductivity of membrane achieves 1.08 mS cm −1 and the electrochemical window is about 4.8 V, which meets the practical requirements of LIBs. Significantly, with LiFePO 4 /Li battery this membrane can run for 230 cycles with a capacity retention of 97.4% and a discharge capacity of 149.0 mAh g −1 , demonstrating the huge potential for high safety and next‐generation LIBs." @default.
- W4377291710 created "2023-05-23" @default.
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- W4377291710 date "2023-05-01" @default.
- W4377291710 modified "2023-10-02" @default.
- W4377291710 title "A biodegradable nano‐composite membrane for high‐safety and durable lithium‐ion batteries" @default.
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- W4377291710 doi "https://doi.org/10.1049/mna2.12168" @default.
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