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- W4377823300 abstract "The oxidative capability of Ni4+ and high operation voltage of nickel-rich LiNi1−x−yCoxMnyO2 (Ni-rich NCM) cause its continuous and deleterious side reactions with electrolyte and irreversible phase transition, which hinder its industrial application. To mitigate these issues, Al (CF3SO3)3 is proposed as a solid electrolyte additive that can be readily oxidized to regulate the cathode-electrolyte interphase (CEI) due to the highest occupied molecular orbital-level of CF3SO3−, meanwhile being confined within the single-crystalline NCM811. CF3SO3− prior to the electrolyte is oxidized upon increasing voltage to produce sulfur components and involve CEI formation. Concurrently, the released Al3+ ions are combined with reactive oxygen from NCM811 particles and HF from the electrolyte to form Al2O3 and AlF3, respectively. A robust sandwich CEI film containing sulfur and aluminum species is formed, which cannot only prevent decomposition of the electrolyte, but also alleviate the formation of inactive rock-salt phase on NCM811 surface. Consequently, such CEI leads to high-performance batteries with a high-capacity retention of 91.5% after 200 cycles under 0.5 C compared to 72.4% of pristine NCM811. This facile and environmentally benign method provides a new avenue to develop high-capacity and durable cathodes for lithium-ion batteries." @default.
- W4377823300 created "2023-05-24" @default.
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- W4377823300 date "2023-05-22" @default.
- W4377823300 modified "2023-09-28" @default.
- W4377823300 title "Regulating Cathode‐Electrolyte Interphase by Confining Functional Aluminum Compound within Ni‐Rich Cathodes" @default.
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- W4377823300 doi "https://doi.org/10.1002/adfm.202301642" @default.
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