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• W4377939145 abstract "The exploration of novel inorganic tellurites is significant because of their promising applications in nonlinear-optical materials and birefringent materials. Herein, three new aluminum/gallium tellurites, namely, NaAl(Te4O10) (1), AgAl(Te4O10) (2), and K2Ga2(HTe6O16)(HTeO3) (3), have been successfully obtained by mild hydrothermal reactions. The isostructural compounds 1 and 2 contain the Te3O8 trimer, while compound 3 contains an unprecedented Te6O16 hexamer. Notably, all three compounds exhibit large birefringence values of over 0.1 at 532 nm, which are currently the largest reported birefringence values among tellurium(IV) oxides without additional anionic groups." @default.
• W4377939145 created "2023-05-25" @default.
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• W4377939145 date "2023-05-24" @default.
• W4377939145 modified "2023-10-14" @default.
• W4377939145 title "AAl(Te₄O₁₀) (A = Na, Ag) and K₂Ga₂(HTe₆O₁₆)(HTeO₃): Three Aluminum/Gallium Tellurites with Large Birefringence and Wide Band Gap" @default.
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• W4377939145 doi "https://doi.org/10.1021/acs.inorgchem.3c01428" @default.
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