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• W4377942351 abstract "Abstract We present here the syntheses and structural characterizations of inorganic polymeric cluster compounds, Cs[Mn(salen)] 3 [{Mo 6 Br 6 Se 2 }(CN) 6 ] ( 1 ) and (H 3 O)(TBA)[Mn(salen)] 2 [{Mo 6 Br 6 Se 2 }(CN) 6 ] ( 2 ) (TBA=tetrabutylammonium ((n‐C 4 H 9 ) 4 N + )), built‐up from [{Mo 6 Br 6 Se 2 }(CN) 6 ] 4− molecular building blocks and Mn(salen) + complexes (salen = salen = N,N′‐bis(salicylidene)ethylenediamine ). The nature of additional counter cations (i. e. Cs + or TBA + ) enables to control the interactions between the [{Mo 6 Br 6 Se 2 }(CN) 6 ] 4− building blocks and the Mn(salen) + groups. Thus, 1 was obtained by slow diffusion of a methanol solution of K 2 Cs 2 [{Mo 6 Br 6 Se 2 }(CN) 6 ] cluster compound into a methanol solution of Mn(salen)ClO 4 . 2 was obtained in a similar way but after the addition of tetrabutylammonium bromide into the solution of Mn(salen)ClO 4 . 1 is a bimetallic 3D coordination compound ( ) and 2 is a bimetallic 2D compound ( ). Structural correlations between 1 and 2 are discussed and compared with relevant examples found in the literature." @default.
• W4377942351 created "2023-05-25" @default.
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• W4377942351 date "2023-06-05" @default.
• W4377942351 modified "2023-09-27" @default.
• W4377942351 title "Playing with [{Mo₆Brⁱ₆Seⁱ₂}(CN)^a₆]⁴⁻ Cluster Building Blocks and Mn(salen)⁺ Nodes for the Crystal Engineering of Inorganic Coordination Polymers" @default.
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• W4377942351 doi "https://doi.org/10.1002/zaac.202300070" @default.
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