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• W4377966139 abstract "The reaction process of ZrC–2ZrB2-based Cu cermets from the (1 − x wt.%)(1B4C–3Zr)–x wt.%Cu system (Zr/B4C = 3 in molar ratio) was explored. Results showed that ZrC and ZrB2 were mostly produced through the dissolution of B4C into a preformed Zr–Cu liquid. With an increase in x, the synthetic ZrC–2ZrB2 and generated heat were reduced. This effect decreased an ability for Zr–Cu liquid to propagate in the reactants, and restrained the dissolution Zr. As a result, the complete synthesis of ZrC–2ZrB2 failed in the systems with a higher Cu content (e.g., 50 wt.%). Furthermore, after the precipitation of ZrC and ZrB2, the liquid surrounding would prevent ZrC and ZrB2 from growing. Increasing Cu content enhanced the amount of Zr–Cu melt. This behavior contributed to a decline in ZrC–2ZrB2 particle sizes, and the production of fine ceramic particles (∼200 nm). It is also revealed that the formation of ZrC–2ZrB2 is a multistep process, which results in the inhomogeneity of ZrC–2ZrB2 particle sizes. A valuable approach was proposed to explore the relationship between reaction process and synthesized products of combustion synthesis-related technique." @default.
• W4377966139 created "2023-05-25" @default.
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• W4377966139 date "2023-06-01" @default.
• W4377966139 modified "2023-10-01" @default.
• W4377966139 title "Reaction Mechanism of Combustion Synthesized ZrC–2ZrB₂-Based Cu Cermets" @default.
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• W4377966139 doi "https://doi.org/10.2320/matertrans.mt-m2022210" @default.
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