FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4378172979> ?p ?o ?g. }

• W4378172979 endingPage "8793" @default.
• W4378172979 startingPage "8789" @default.
• W4378172979 abstract "Here, we investigate the stereoelectronic requirements of a family of Fe/Co6Se8 molecular clusters to achieve a Goldilocks regime of substrate affinity for the catalytic coupling of tosyl azide and tert-butyl isocyanide. The reactivity of a catalytically competent iron-nitrenoid intermediate, observed in situ, is explored toward nitrene transfer and hydrogen-atom abstraction. The dual role of isocyanide, which, on the one hand, prevents catalyst degradation but, in large amounts, slows down reactivity, is exposed. The impact of distal changes (the number of neighboring active sites and the identity of supporting ligands) on the substrate affinity, electronic properties, and catalytic activity is investigated. Overall, the study reveals that the dynamic, push-pull interactions between the substrate (tBuNC), active site (Fe), and support (Co6Se8) create a regime where increased substrate activation occurs with facile dissociation." @default.
• W4378172979 created "2023-05-26" @default.
• W4378172979 creator A5000010710 @default.
• W4378172979 creator A5048938777 @default.
• W4378172979 creator A5057933184 @default.
• W4378172979 creator A5061928992 @default.
• W4378172979 creator A5083375868 @default.
• W4378172979 date "2023-05-25" @default.
• W4378172979 modified "2023-10-16" @default.
• W4378172979 title "Metal/Support Interactions Regulate Substrate Binding in Fe/Co/Se Cluster Catalysts" @default.
• W4378172979 cites W1816450589 @default.
• W4378172979 cites W1974115717 @default.
• W4378172979 cites W1976205221 @default.
• W4378172979 cites W2008850528 @default.
• W4378172979 cites W2021657198 @default.
• W4378172979 cites W2028957948 @default.
• W4378172979 cites W2039397684 @default.
• W4378172979 cites W2044767584 @default.
• W4378172979 cites W2071982166 @default.
• W4378172979 cites W2094112103 @default.
• W4378172979 cites W2235373962 @default.
• W4378172979 cites W2319591706 @default.
• W4378172979 cites W2332269594 @default.
• W4378172979 cites W2408830764 @default.
• W4378172979 cites W2443960070 @default.
• W4378172979 cites W2742295368 @default.
• W4378172979 cites W2767523683 @default.
• W4378172979 cites W2890982411 @default.
• W4378172979 cites W2912466544 @default.
• W4378172979 cites W2952721878 @default.
• W4378172979 cites W2982215879 @default.
• W4378172979 cites W2983632217 @default.
• W4378172979 cites W2986466158 @default.
• W4378172979 cites W2991548882 @default.
• W4378172979 cites W3080610334 @default.
• W4378172979 cites W3140204406 @default.
• W4378172979 cites W3156654680 @default.
• W4378172979 cites W4200383516 @default.
• W4378172979 cites W4205310217 @default.
• W4378172979 cites W4281250328 @default.
• W4378172979 cites W4283457503 @default.
• W4378172979 cites W4297519300 @default.
• W4378172979 cites W4309924771 @default.
• W4378172979 cites W566353445 @default.
• W4378172979 doi "https://doi.org/10.1021/acs.inorgchem.3c01601" @default.
• W4378172979 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37227222" @default.
• W4378172979 hasPublicationYear "2023" @default.
• W4378172979 type Work @default.
• W4378172979 citedByCount "0" @default.
• W4378172979 crossrefType "journal-article" @default.
• W4378172979 hasAuthorship W4378172979A5000010710 @default.
• W4378172979 hasAuthorship W4378172979A5048938777 @default.
• W4378172979 hasAuthorship W4378172979A5057933184 @default.
• W4378172979 hasAuthorship W4378172979A5061928992 @default.
• W4378172979 hasAuthorship W4378172979A5083375868 @default.
• W4378172979 hasConcept C102931765 @default.
• W4378172979 hasConcept C111368507 @default.
• W4378172979 hasConcept C127313418 @default.
• W4378172979 hasConcept C142724271 @default.
• W4378172979 hasConcept C161790260 @default.
• W4378172979 hasConcept C178790620 @default.
• W4378172979 hasConcept C185592680 @default.
• W4378172979 hasConcept C204787440 @default.
• W4378172979 hasConcept C21951064 @default.
• W4378172979 hasConcept C2776910235 @default.
• W4378172979 hasConcept C2777289219 @default.
• W4378172979 hasConcept C38489247 @default.
• W4378172979 hasConcept C71240020 @default.
• W4378172979 hasConcept C71924100 @default.
• W4378172979 hasConcept C75473681 @default.
• W4378172979 hasConceptScore W4378172979C102931765 @default.
• W4378172979 hasConceptScore W4378172979C111368507 @default.
• W4378172979 hasConceptScore W4378172979C127313418 @default.
• W4378172979 hasConceptScore W4378172979C142724271 @default.
• W4378172979 hasConceptScore W4378172979C161790260 @default.
• W4378172979 hasConceptScore W4378172979C178790620 @default.
• W4378172979 hasConceptScore W4378172979C185592680 @default.
• W4378172979 hasConceptScore W4378172979C204787440 @default.
• W4378172979 hasConceptScore W4378172979C21951064 @default.
• W4378172979 hasConceptScore W4378172979C2776910235 @default.
• W4378172979 hasConceptScore W4378172979C2777289219 @default.
• W4378172979 hasConceptScore W4378172979C38489247 @default.
• W4378172979 hasConceptScore W4378172979C71240020 @default.
• W4378172979 hasConceptScore W4378172979C71924100 @default.
• W4378172979 hasConceptScore W4378172979C75473681 @default.
• W4378172979 hasFunder F4320306076 @default.
• W4378172979 hasFunder F4320306487 @default.
• W4378172979 hasFunder F4320337393 @default.
• W4378172979 hasIssue "23" @default.
• W4378172979 hasLocation W43781729791 @default.
• W4378172979 hasLocation W43781729792 @default.
• W4378172979 hasOpenAccess W4378172979 @default.
• W4378172979 hasPrimaryLocation W43781729791 @default.
• W4378172979 hasRelatedWork W1967533796 @default.
• W4378172979 hasRelatedWork W1974376097 @default.
• W4378172979 hasRelatedWork W1995669378 @default.
• W4378172979 hasRelatedWork W2010368168 @default.
• W4378172979 hasRelatedWork W2070363224 @default.

• next