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• W4378193742 abstract "Luminescent Cu(I) complexes have drawn considerable attention as alternative materials to precious transition metal complexes due to their low cost and electron configuration. Discrete heteroleptic diamine-diphosphine copper(I) complexes have been investigated owing to their outstanding photophysical features. However, heteroleptic copper(I) coordination polymers remain mostly unexplored. Herein, we report the synthesis and photophysical characterization of a heteroleptic copper(I) coordination polymer by employing bidentate oxybis(2,1-phenylene)bis(diphenylphosphine) (POP) diphosphine and nitrogen heterocyclic 5-[4-(1-imidazolyl)phenyl]-2H-tetrazole (ipt) as ligands. By utilizing the mixed-solvent strategy, a one-dimensional (1D) linear chain was constructed under solvothermal reaction conditions. Temperature-dependent emission spectra combined with decay time measurements demonstrate that emission originated from triplet phosphorescence at ambient temperature." @default.
• W4378193742 created "2023-05-26" @default.
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• W4378193742 date "2023-04-18" @default.
• W4378193742 modified "2023-09-27" @default.
• W4378193742 title "Synthesis and characterization of a luminescent diphosphine and aromatic <i>N</i>-heterocyclic copper(I) coordination polymer" @default.
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• W4378193742 doi "https://doi.org/10.1080/00958972.2023.2214295" @default.
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