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- W4378347791 abstract "Base-mediated rearrangement of 1,3-dithianyl-substituted propargylamines in DMF via expansion of the dithiane ring has been reported. The rearrangement provided 9-membered amino-functionalized sulfur-containing heterocycles (dithionine derivatives) in good yields under mild conditions. Propargylamines bearing 5-membered 1,3-dithiolane and 7-membered 1,3-dithiepane rings rearranged in a similar manner yielding 8- and 10-membered S,S-heterocycles, respectively." @default.
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- W4378347791 date "2023-05-26" @default.
- W4378347791 modified "2023-10-14" @default.
- W4378347791 title "Base-Mediated Rearrangement of α-Dithioacetyl Propargylamines via Expansion of Dithioacetyl Ring: Synthesis of Medium-Sized <i>S,S</i>-Heterocycles" @default.
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- W4378347791 doi "https://doi.org/10.1021/acs.orglett.3c01118" @default.
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