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- W4378364049 abstract "Abstract A synthetic strategy that exploits the formation of an electron donor‐acceptor (EDA) complex between a tertiary α‐ silylamine and 1‐iodoalkyne under UVA LED (light emitting diode) light ( λ max =365 nm) to prepare propargyl amines is described. The site‐ and chemoselective synthetic method was shown to tolerate a wide range of functional groups to give the α ‐alkynylation product in good to excellent yields. The usefulness of the C(sp)–C(sp 3 ) bond formation protocol was also exemplified by the late‐stage functionalisation of a variety of natural products and bioactive compounds." @default.
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- W4378364049 date "2023-06-20" @default.
- W4378364049 modified "2023-10-14" @default.
- W4378364049 title "UVA LED Light Promoted Cross‐Coupling of Tertiary <i>α</i>‐Silylamines with 1‐Iodoalkynes" @default.
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- W4378364049 doi "https://doi.org/10.1002/ajoc.202300221" @default.
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